{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:36:40Z","timestamp":1785407800799,"version":"3.56.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2023,1,17]],"date-time":"2023-01-17T00:00:00Z","timestamp":1673913600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,1,17]],"date-time":"2023-01-17T00:00:00Z","timestamp":1673913600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Ciencia y Tecnolog\u00eda","doi-asserted-by":"publisher","award":["268178"],"award-info":[{"award-number":["268178"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,1,10]]},"published-print":{"date-parts":[[2023,2,1]]},"abstract":"<jats:p>\n                    The title Sn\n                    <jats:sup>IV<\/jats:sup>\n                    complex, [Sn(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    Cl(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    P)], is a formal adduct between triphenyl phosphate (PhO)\n                    <jats:sub>3<\/jats:sub>\n                    P=O and the stannane derivative chloridotriphenyltin, SnPh\n                    <jats:sub>3<\/jats:sub>\n                    Cl. The structure refinement reveals that this molecule displays the largest Sn\u2014O bond length for compounds including the\n                    <jats:italic>X<\/jats:italic>\n                    =O\u2192SnPh\n                    <jats:sub>3<\/jats:sub>\n                    Cl fragment (\n                    <jats:italic>X<\/jats:italic>\n                    = P, S, C, or V), 2.6644\u2005(17)\u2005\u00c5. However, an AIM topology analysis based on the wavefunction calculated from the refined X-ray structure shows the presence of a bond critical point (3,\u22121), lying on the interbasin surface separating the coordinated phosphate O atom and the Sn atom. This study thus shows that an actual polar covalent bond is formed between (PhO)\n                    <jats:sub>3<\/jats:sub>\n                    P=O and SnPh\n                    <jats:sub>3<\/jats:sub>\n                    Cl moieties.\n                  <\/jats:p>","DOI":"10.1107\/s2056989023000270","type":"journal-article","created":{"date-parts":[[2023,1,17]],"date-time":"2023-01-17T03:41:40Z","timestamp":1673926900000},"page":"99-102","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-\u03ba\n                    <i>O<\/i>\n                    )tin(IV)"],"prefix":"10.1107","volume":"79","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7241-0365","authenticated-orcid":true,"given":"Serigne Fallou","family":"Pouye","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9209-7580","authenticated-orcid":true,"given":"Sylvain","family":"Bern\u00e8s","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03p2z7827","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lamine","family":"Yaffa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Waly","family":"Diallo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ibrahima","family":"Ciss\u00e9","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0001-9484","authenticated-orcid":true,"given":"Cheikh Abdoul Khadir","family":"Diop","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mamadou","family":"Sidib\u00e9","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libasse","family":"Diop","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,1,17]]},"reference":[{"key":"zl4052_bb1","doi-asserted-by":"crossref","first-page":"10391","DOI":"10.1021\/jp906341r","volume":"113","author":"Bader","year":"2009","journal-title":"J. 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