{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:36:51Z","timestamp":1785407811496,"version":"3.56.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2023,8,15]],"date-time":"2023-08-15T00:00:00Z","timestamp":1692057600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,8,15]],"date-time":"2023-08-15T00:00:00Z","timestamp":1692057600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100019220","name":"Salahaddin University-Erbil","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100019220","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,8,5]]},"published-print":{"date-parts":[[2023,9,1]]},"abstract":"<jats:p>\n                    3-Methylbenzoic acid (3-mbH) and 2,2\u2032-bipyridine (bipy) reacted with a copper(II) salt forming a new mixed ligand complex, aqua(2,2\u2032-bipyridine-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032)bis(3-methylbenzoato)-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>O<\/jats:italic>\n                    ,\n                    <jats:italic>O<\/jats:italic>\n                    \u2032;\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    -copper(II) 0.68-hydrate, [Cu(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )(H\n                    <jats:sub>2<\/jats:sub>\n                    O)]\u00b70.68H\n                    <jats:sub>2<\/jats:sub>\n                    O or [Cu(3-mb)\n                    <jats:sub>2<\/jats:sub>\n                    (bipy)(H\n                    <jats:sub>2<\/jats:sub>\n                    O)]\u00b70.68H\n                    <jats:sub>2<\/jats:sub>\n                    O. The coordination environment of Cu\n                    <jats:sup>II<\/jats:sup>\n                    is a distorted octahedron. The metal atom is attached to two 3-mb moieties, which bind in monodentate and bidentate fashions. One of the 3-mb units is disordered. The coordination environment is completed by one bipy ligand and a water molecule. A second water molecule is outside the coordination sphere of the Cu\n                    <jats:sup>II<\/jats:sup>\n                    atom and its occupancy refined to 0.68. The structure consists of chains along the\n                    <jats:italic>b-<\/jats:italic>\n                    axis direction formed by complex units joined\n                    <jats:italic>via<\/jats:italic>\n                    hydrogen bonds between the coordinated water molecule and an O atom of a coordinated 3-mb unit. Hirshfeld surface analysis indicates that the most abundant contacts are H...H (56.8%), H...C\/C...H (21.7%) and H...O\/O...H (13.7%).\n                  <\/jats:p>","DOI":"10.1107\/s2056989023006904","type":"journal-article","created":{"date-parts":[[2023,8,9]],"date-time":"2023-08-09T00:57:21Z","timestamp":1691542641000},"page":"804-807","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of a copper(II) complex involving 3-methylbenzoate and 2,2\u2032-bipyridine ligands"],"prefix":"10.1107","volume":"79","author":[{"given":"Adnan","family":"Qadir","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02124dd11","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,8,15]]},"reference":[{"key":"dj2063_bb1","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/j.molstruc.2010.07.014","volume":"980","author":"Abuhijleh","year":"2010","journal-title":"J. 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