{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T13:38:48Z","timestamp":1768829928319,"version":"3.49.0"},"reference-count":32,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2023,8,23]],"date-time":"2023-08-23T00:00:00Z","timestamp":1692748800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,8,23]],"date-time":"2023-08-23T00:00:00Z","timestamp":1692748800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,8,7]]},"published-print":{"date-parts":[[2023,9,1]]},"abstract":"<jats:p>The asymmetric units of the isostructural compounds (1,4,8,11-tetraazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>)nickel(II) tetraiodidocadmate(II), [Ni(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)][CdI<jats:sub>4<\/jats:sub>] (<jats:bold>I<\/jats:bold>), and triiodido-1\u03ba<jats:sup>3<\/jats:sup>\n                  <jats:italic>I<\/jats:italic>-\u03bc-iodido-(1,4,8,11-tetraazacyclotetradecane-2\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>)cadmium(II)zinc(II), [CdZnI<jats:sub>4<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)] (<jats:bold>II<\/jats:bold>) (C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub> = 1,4,8,11-tetraazacyclotetradecane, cyclam, <jats:italic>L<\/jats:italic>), consist of the centrosymmetric macrocyclic cation [<jats:italic>M<\/jats:italic>(<jats:italic>L<\/jats:italic>)]<jats:sup>2+<\/jats:sup> [<jats:italic>M<\/jats:italic> = Ni<jats:sup>II<\/jats:sup> or Zn<jats:sup>II<\/jats:sup>] with the metal ion lying on a twofold screw axis, and the tetraiodocadmate anion [CdI<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> located on the mirror plane. In <jats:bold>I<\/jats:bold>, the anion acts as an uncoordinated counter-ion while in <jats:bold>II<\/jats:bold> it is bound to the Zn<jats:sup>II<\/jats:sup> atom <jats:italic>via<\/jats:italic> one of the iodide atoms, thus forming an electroneutral heterobimetallic complex [Zn(<jats:italic>L<\/jats:italic>)(CdI<jats:sub>4<\/jats:sub>)]. The Ni<jats:sup>II<\/jats:sup> and Zn<jats:sup>II<\/jats:sup> ions are coordinated in a square-planar manner by the four secondary N atoms of the macrocyclic ligand <jats:italic>L<\/jats:italic>, which adopts the most energetically stable <jats:italic>trans<\/jats:italic>-III conformation. The [CdI<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anions in <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold> are structurally very similar and represent slightly deformed tetrahedrons with average Cd\u2014I bond lengths and I\u2014Cd\u2014I angles of <jats:italic>ca<\/jats:italic> 2.79\u2005\u00c5 and 109.6\u00b0, respectively. The supramolecular organization of the complexes under consideration in the crystals is very similar and is determined by the hydrogen-bonding interactions between the secondary amino groups of the ligand <jats:italic>L<\/jats:italic> in the [<jats:italic>M<\/jats:italic>(<jats:italic>L<\/jats:italic>)]<jats:sup>2+<\/jats:sup> cations and iodide atoms of the [CdI<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion. In particular, the alternating cations and anions form chains running along the <jats:italic>b-<\/jats:italic>axis direction that are arranged into di-periodic sheets oriented parallel to the (101) and (\\overline{1}01) planes. Because both kinds of sheets are built from the same cations and anions, this feature provides the three-dimensional coherence of the crystals of <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold>.<\/jats:p>","DOI":"10.1107\/s2056989023007004","type":"journal-article","created":{"date-parts":[[2023,8,9]],"date-time":"2023-08-09T05:04:35Z","timestamp":1691557475000},"page":"821-826","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structures of the complexes containing macrocyclic cations [<i>M<\/i>(cyclam)]<sup>2+<\/sup> (<i>M<\/i> = Ni, Zn) and tetraiodidocadmate(2\u2013) anion"],"prefix":"10.1107","volume":"79","author":[{"given":"Irina L.","family":"Andriichuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1222-4373","authenticated-orcid":true,"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,8,23]]},"reference":[{"key":"ex2074_bb1","doi-asserted-by":"crossref","first-page":"2493","DOI":"10.1039\/dt9910002493","author":"Adam","year":"1991","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ex2074_bb2","doi-asserted-by":"crossref","unstructured":"Bach, A., Hoyer, M. & Hartl, H. (1997). Z. Naturforsch. B: Chem. Sci. 52, 1497-1500.","DOI":"10.1515\/znb-1997-1210"},{"key":"ex2074_bb3","doi-asserted-by":"crossref","first-page":"1099","DOI":"10.1021\/ic3024056","volume":"52","author":"Bao","year":"2013","journal-title":"Inorg. Chem."},{"key":"ex2074_bb4","doi-asserted-by":"crossref","first-page":"4197","DOI":"10.1021\/ic00243a028","volume":"25","author":"Barefield","year":"1986","journal-title":"Inorg. Chem."},{"key":"ex2074_bb5","doi-asserted-by":"crossref","first-page":"1102","DOI":"10.1021\/ic50030a003","volume":"4","author":"Bosnich","year":"1965","journal-title":"Inorg. Chem."},{"key":"ex2074_bb6","doi-asserted-by":"crossref","first-page":"1109","DOI":"10.1021\/ic50030a004","volume":"4","author":"Bosnich","year":"1965","journal-title":"Inorg. Chem."},{"key":"ex2074_bb7","doi-asserted-by":"crossref","first-page":"4876","DOI":"10.1021\/ic0103446","volume":"40","author":"Colacio","year":"2001","journal-title":"Inorg. Chem."},{"key":"ex2074_bb8","doi-asserted-by":"crossref","first-page":"18107","DOI":"10.1039\/D1DT03014K","volume":"50","author":"Danker","year":"2021","journal-title":"Dalton Trans."},{"key":"ex2074_bb9","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1016\/j.molstruc.2008.12.027","volume":"921","author":"Dobrzycki","year":"2009","journal-title":"J. Mol. Struct."},{"key":"ex2074_bb10","doi-asserted-by":"crossref","first-page":"1185","DOI":"10.1107\/S2056989021011166","volume":"77","author":"Gavrish","year":"2021","journal-title":"Acta Cryst. E"},{"key":"ex2074_bb11","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"ex2074_bb12","unstructured":"Heinemann, F. W., Schickaneder, C. & Alsfasser, R. (2022). CSD Communication (refcode QASKOO). CCDC, Cambridge, England."},{"key":"ex2074_bb13","doi-asserted-by":"crossref","first-page":"5418","DOI":"10.1021\/acs.inorgchem.9b03735","volume":"59","author":"Horii","year":"2020","journal-title":"Inorg. Chem."},{"key":"ex2074_bb14","doi-asserted-by":"crossref","first-page":"2634","DOI":"10.1021\/acs.inorgchem.6b00021","volume":"55","author":"Lee","year":"2016","journal-title":"Inorg. Chem."},{"key":"ex2074_bb15","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"ex2074_bb16","doi-asserted-by":"crossref","first-page":"490","DOI":"10.1107\/S2056989022003759","volume":"78","author":"N\u00e4ther","year":"2022","journal-title":"Acta Cryst. E"},{"key":"ex2074_bb17","doi-asserted-by":"crossref","first-page":"1444","DOI":"10.1002\/ejic.200500947","author":"Notni","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ex2074_bb18","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1107\/S2052252517015081","volume":"5","author":"Park","year":"2018","journal-title":"IUCrJ"},{"key":"ex2074_bb19","doi-asserted-by":"crossref","first-page":"6012","DOI":"10.1021\/cg501194n","volume":"14","author":"Park","year":"2014","journal-title":"Cryst. Growth Des."},{"key":"ex2074_bb20","first-page":"435","volume":"39","author":"Porai-Koshits","year":"1994","journal-title":"Zh. Neorg. Khim."},{"key":"ex2074_bb21","doi-asserted-by":"crossref","first-page":"1175","DOI":"10.1107\/S0108270183007817","volume":"39","author":"Prasad","year":"1983","journal-title":"Acta Cryst. C"},{"key":"ex2074_bb22","unstructured":"Rigaku OD (2022). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England."},{"key":"ex2074_bb23","doi-asserted-by":"crossref","first-page":"7665","DOI":"10.1039\/D1TC01526E","volume":"9","author":"Rok","year":"2021","journal-title":"J. Mater. Chem. C."},{"key":"ex2074_bb24","doi-asserted-by":"crossref","first-page":"605","DOI":"10.1007\/s11224-010-9730-7","volume":"22","author":"Satapathi","year":"2011","journal-title":"Struct. Chem."},{"key":"ex2074_bb25","doi-asserted-by":"crossref","first-page":"4630","DOI":"10.1021\/ic050014b","volume":"44","author":"Seitz","year":"2005","journal-title":"Inorg. Chem."},{"key":"ex2074_bb26","first-page":"922","volume":"57","author":"Sharutin","year":"2012","journal-title":"Russ. J. Inorg. Chem."},{"key":"ex2074_bb27","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ex2074_bb28","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ex2074_bb29","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"ex2074_bb30","unstructured":"Yatsimirskii, K. B. & Lampeka, Ya. D. (1985). Physicochemistry of Metal Complexes with Macrocyclic Ligands. Kiev: Naukova Dumka. (In Russian.)"},{"key":"ex2074_bb31","doi-asserted-by":"crossref","first-page":"1987","DOI":"10.1016\/j.ica.2006.10.014","volume":"360","author":"Yu","year":"2007","journal-title":"Inorg. Chim. Acta"},{"key":"ex2074_bb32","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1002\/ejic.201801176","author":"Zhang","year":"2019","journal-title":"Eur. J. Inorg. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2023\/09\/00\/ex2074\/ex2074.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2023\/09\/00\/ex2074\/ex2074.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:26:45Z","timestamp":1736767605000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989023007004"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,23]]},"references-count":32,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2023,9]]}},"alternative-id":["S2056989023007004"],"URL":"https:\/\/doi.org\/10.1107\/s2056989023007004","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989023007004\/ex2074sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989023007004\/ex2074Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989023007004\/ex2074IIsup3.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,23]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?ex2074","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"18 July 2023","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"7 August 2023","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"23 August 2023","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ex2074"}},{"value":"\u00a9 2023 Andriichuk et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}