{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T16:19:00Z","timestamp":1785428340742,"version":"3.56.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2023,8,17]],"date-time":"2023-08-17T00:00:00Z","timestamp":1692230400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,8,17]],"date-time":"2023-08-17T00:00:00Z","timestamp":1692230400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,8,11]]},"published-print":{"date-parts":[[2023,9,1]]},"abstract":"<jats:p>\n                    The title indole derivative, C\n                    <jats:sub>24<\/jats:sub>\n                    H\n                    <jats:sub>17<\/jats:sub>\n                    Br\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    S, crystallizes with a partial occupancy [0.585\u2005(4)] CHCl\n                    <jats:sub>3<\/jats:sub>\n                    solvent molecule. The dihedral angles between the indole ring system and pendant nitrobenzodioxolane rings system and phenylsulfonyl ring are 4.81\u2005(14) and 72.24\u2005(19)\u00b0, respectively. In the crystal, the indole molecules are linked to each other and to the chloroform molecule by weak C\u2014H...O, C\u2014H...Cl, C\u2014H...\u03c0, C\u2014Br...\u03c0 and C\u2014Cl...\u03c0 and aromatic \u03c0\u2013\u03c0 stacking interactions. A Hirshfeld surface analysis was carried out and the intermolecular contacts with the most significant contributions are H...O\/O...H (24.3%), H...H (18.4%), Br...H\/H...Br (16.8%) and C...H\/H...C (8.4%).\n                  <\/jats:p>","DOI":"10.1107\/s2056989023007120","type":"journal-article","created":{"date-parts":[[2023,8,16]],"date-time":"2023-08-16T11:30:53Z","timestamp":1692185453000},"page":"813-816","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of 3-(bromomethyl)-2-[1,2-dibromo-2-(6-nitrobenzo[\n                    <i>d<\/i>\n                    ][1,3]dioxol-5-yl)ethyl]-1-(phenylsulfonyl)-1\n                    <i>H<\/i>\n                    -indole chloroform 0.585-solvate"],"prefix":"10.1107","volume":"79","author":[{"given":"Nagaraj","family":"Achyuta","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Somarathinam","family":"Kanagasabai","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pavunkumar","family":"Vinayagam","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arasambattu K.","family":"Mohanakrishnan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6242-1212","authenticated-orcid":true,"given":"Namasivayam","family":"Gautham","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Krishnasamy","family":"Gunasekaran","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,8,17]]},"reference":[{"key":"hb8071_bb1","doi-asserted-by":"crossref","first-page":"S1","DOI":"10.1039\/p298700000s1","volume":"2","author":"Allen","year":"1987","journal-title":"J. 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