{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T18:33:54Z","timestamp":1778697234915,"version":"3.51.4"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,9,15]]},"published-print":{"date-parts":[[2023,10,1]]},"abstract":"<jats:p>In the title compound, [Fe<jats:sup>II<\/jats:sup>(C<jats:sub>44<\/jats:sub>H<jats:sub>24<\/jats:sub>Cl<jats:sub>4<\/jats:sub>N<jats:sub>4<\/jats:sub>)(C<jats:sub>5<\/jats:sub>H<jats:sub>9<\/jats:sub>N)<jats:sub>2<\/jats:sub>] or [Fe<jats:sup>II<\/jats:sup>(TClPP)(<jats:italic>t<\/jats:italic>-BuNC)<jats:sub>2<\/jats:sub>] [where TClPP and <jats:italic>t<\/jats:italic>-BuNC are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and <jats:italic>tert-<\/jats:italic>butyl isocyanide ligands, respectively], the metal ion lies on an inversion center and is octahedrally coordinated by the N atoms of the porphyrin ring in the equatorial plane and by carbon atoms of the <jats:italic>trans t<\/jats:italic>-BuNC ligands in the axial sites. The Fe\u2014N bond length of 2.0074\u2005(14)\u2005\u00c5 suggests a low-spin complex (<jats:italic>S<\/jats:italic> = 0). The crystal packing of the title compound is sustained by C\u2014H...Cl, C\u2014H...N and C<jats:sup>__<\/jats:sup>H...<jats:italic>Cg<\/jats:italic> (<jats:italic>Cg<\/jats:italic> = the centroid of a pyrrole ring of the TClPP porphyrinate) interactions, leading to a three-dimensional network. The Hirshfeld surface (HS) analysis indicates that 61.4% of the intermolecular interactions are from H...H contacts while other contributions are from C...H\/H...C, O...H\/H...O and N...H\/H...N interactions, which comprise 21.3%, 13.3% and 3.6% of the HS, respectively.<\/jats:p>","DOI":"10.1107\/s2056989023008083","type":"journal-article","created":{"date-parts":[[2023,9,21]],"date-time":"2023-09-21T05:03:36Z","timestamp":1695272616000},"page":"931-935","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and crystal structure of bis(<i>tert<\/i>-butyl isocyanide-\u03ba<i>C<\/i>)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>]iron(II)"],"prefix":"10.1107","volume":"79","author":[{"given":"Soumaya","family":"Nasri","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,9,26]]},"reference":[{"key":"hb8075_bb1","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1021\/jo01288a053","volume":"32","author":"Adler","year":"1967","journal-title":"J. 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