{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:15:22Z","timestamp":1785406522018,"version":"3.56.0"},"reference-count":34,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T00:00:00Z","timestamp":1695686400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"The Algerian MESRS"},{"name":"the Algerian DGRSDT"},{"name":"PRFU project","award":["B00L01UN190120230003"],"award-info":[{"award-number":["B00L01UN190120230003"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,9,18]]},"published-print":{"date-parts":[[2023,10,1]]},"abstract":"<jats:p>\n                    The title compound, [Fe(C\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b72H\n                    <jats:sub>2<\/jats:sub>\n                    O, has been synthesized solvothermally and characterized by single-crystal X-ray diffraction. The octahedral iron coordination polyhedron contains two di(pyrimidin-2-yl)amine ligands coordinated in a bidentate fashion, and two monodentate dicyanimido ligands, each coordinated\n                    <jats:italic>via<\/jats:italic>\n                    a terminal N atom, with the latter in a\n                    <jats:italic>cis<\/jats:italic>\n                    orientation. The ligand configuration about the iron atom is chiral, although the compound crystallizes as a racemic mixture: the Fe\u2014N distances (&gt; 2.07\u2005\u00c5) are characteristic of high-spin iron(II). In the crystal, an extensive series of N\u2014H...N, O\u2014H...N and O\u2014H...O hydrogen bonds links the independent molecular components into a three-dimensional framework. The H atoms of both water molecules are disordered. The structure also features some \u03c0\u2013\u03c0 and anion\u2013\u03c0 interactions. The intermolecular interactions were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots. Comparisons are made with some related compounds.\n                  <\/jats:p>","DOI":"10.1107\/s2056989023008186","type":"journal-article","created":{"date-parts":[[2023,9,20]],"date-time":"2023-09-20T11:00:19Z","timestamp":1695207619000},"page":"936-941","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Racemic\n                    <i>cis<\/i>\n                    -bis[bis(pyrimidin-2-yl)amine-\u03ba\n                    <i>N<\/i>\n                    ]bis(dicyanamido-\u03ba\n                    <i>N<\/i>\n                    <sup>1<\/sup>\n                    )iron(II) dihydrate: synthesis, crystal structure and Hirshfeld surface analysis"],"prefix":"10.1107","volume":"79","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5740-3394","authenticated-orcid":true,"given":"Yaakoub","family":"Saadallah","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8160-3852","authenticated-orcid":true,"given":"Zouaoui","family":"Setifi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2655-0313","authenticated-orcid":true,"given":"Christian","family":"Jelsch","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04vfs2w97","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9860-9310","authenticated-orcid":true,"given":"Fatima","family":"Setifi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9777-2653","authenticated-orcid":true,"given":"Mohammed Hadi","family":"Al-Douh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Achouak","family":"Satour","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7621-7538","authenticated-orcid":true,"given":"Christopher","family":"Glidewell","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,9,26]]},"reference":[{"key":"hb8076_bb1","doi-asserted-by":"crossref","first-page":"348","DOI":"10.1107\/S2053229619002444","volume":"75","author":"Addala","year":"2019","journal-title":"Acta Cryst. 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