{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:21:17Z","timestamp":1736832077060,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2023,10,31]],"date-time":"2023-10-31T00:00:00Z","timestamp":1698710400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,10,31]],"date-time":"2023-10-31T00:00:00Z","timestamp":1698710400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["22BF037-03","22BF037-09"],"award-info":[{"award-number":["22BF037-03","22BF037-09"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,10,23]]},"published-print":{"date-parts":[[2023,11,1]]},"abstract":"<jats:p>In the crystal structure of the title compound, [Cu(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>N<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>], the Cu<jats:sup>II<\/jats:sup> atom is situated on an inversion center (Wyckoff position 2<jats:italic>c<\/jats:italic> of space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>n<\/jats:italic>) and shows an octahedral [N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>] coordination environment. The axial positions are occupied by O atoms of nitrate anions, while the equatorial positions are taken up by the N atoms of four 3-aminopyrazole ligands. As a result of the tautomerism of the latter, two coordinate with the N<jats:sup>1<\/jats:sup>-atom of 3-aminopyrazole while the other two with the N<jats:sup>2<\/jats:sup>-atom. The presence of pyrrole-like N\u2014H groups and amine substituents as donor groups leads to numerous intra- and intermolecular hydrogen-bonding interactions, which were quantified by Hirshfeld surface analysis.<\/jats:p>","DOI":"10.1107\/s2056989023009295","type":"journal-article","created":{"date-parts":[[2023,10,31]],"date-time":"2023-10-31T09:24:04Z","timestamp":1698744244000},"page":"1100-1103","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of bis(3-aminopyrazole-\u03ba<i>N<\/i>\n                  <sup>1<\/sup>)bis(3-aminopyrazole-\u03ba<i>N<\/i>\n                  <sup>2<\/sup>)bis(nitrato-\u03ba<i>O<\/i>)copper(II)"],"prefix":"10.1107","volume":"79","author":[{"given":"Olesia I.","family":"Kucheriv","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina A.","family":"Golenya","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4152-7891","authenticated-orcid":true,"given":"Olena","family":"Prysiazhna","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sofiia V.","family":"Partsevska","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0944-6300","authenticated-orcid":true,"given":"Il'ya A.","family":"Gural'skiy","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,10,31]]},"reference":[{"key":"wm5699_bb1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. 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