{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:30:31Z","timestamp":1785421831167,"version":"3.56.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2023,11,14]],"date-time":"2023-11-14T00:00:00Z","timestamp":1699920000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,11,14]],"date-time":"2023-11-14T00:00:00Z","timestamp":1699920000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["22BF037-03"],"award-info":[{"award-number":["22BF037-03"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["22BF037-04"],"award-info":[{"award-number":["22BF037-04"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["22BF037-09"],"award-info":[{"award-number":["22BF037-09"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,11,8]]},"published-print":{"date-parts":[[2023,12,1]]},"abstract":"<jats:p>\n                    The reaction of cadmium bromide tetrahydrate with 3-aminopyrazole (3-apz) in ethanolic solution leads to tautomerization of the ligand and the formation of crystals of the title compound,\n                    <jats:italic>catena<\/jats:italic>\n                    -poly[[dibromidocadmium(II)]-bis(\u03bc-3-amino-1\n                    <jats:italic>H<\/jats:italic>\n                    -pyrazole)-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    :\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    ;\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    :\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    ], [CdBr\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    or [CdBr\n                    <jats:sub>2<\/jats:sub>\n                    (3-apz)\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    . Its asymmetric unit consists of a half of a Cd\n                    <jats:sup>2+<\/jats:sup>\n                    cation, a bromide anion and a 3-apz molecule. The Cd\n                    <jats:sup>2+<\/jats:sup>\n                    cations are coordinated by two bromide anions and two 3-apz ligands, generating\n                    <jats:italic>trans<\/jats:italic>\n                    -CdN\n                    <jats:sub>4<\/jats:sub>\n                    Br\n                    <jats:sub>2<\/jats:sub>\n                    octahedra, which are linked into chains by pairs of the bridging ligands. In the crystal, the ligand molecules and bromide anions of neighboring chains are linked through interchain hydrogen bonds into a two-dimensional network. The intermolecular contacts were quantified using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative quantitative contributions of the weak intermolecular contacts.\n                  <\/jats:p>","DOI":"10.1107\/s2056989023009751","type":"journal-article","created":{"date-parts":[[2023,11,14]],"date-time":"2023-11-14T04:02:38Z","timestamp":1699934558000},"page":"1151-1154","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of polymeric bis(3-amino-1\n                    <i>H<\/i>\n                    -pyrazole)cadmium dibromide"],"prefix":"10.1107","volume":"79","author":[{"given":"Iryna S.","family":"Kuzevanova","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleksandr S.","family":"Vynohradov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vadim A.","family":"Pavlenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey O.","family":"Malinkin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0561n6946","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1092-8035","authenticated-orcid":true,"given":"Igor O.","family":"Fritsky","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maksym","family":"Seredyuk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,11,14]]},"reference":[{"key":"tx2078_bb1","doi-asserted-by":"crossref","first-page":"6814","DOI":"10.1021\/ja00175a012","volume":"112","author":"Chang","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"tx2078_bb2","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"tx2078_bb3","doi-asserted-by":"crossref","first-page":"1035","DOI":"10.1039\/c39950001035","author":"Drew","year":"1995","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"tx2078_bb4","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"tx2078_bb5","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1016\/j.ccr.2014.08.006","volume":"289-290","author":"Kershaw Cook","year":"2015","journal-title":"Coord. Chem. Rev."},{"key":"tx2078_bb6","doi-asserted-by":"crossref","first-page":"121789","DOI":"10.1016\/j.ica.2023.121789","volume":"560","author":"Parshad","year":"2024","journal-title":"Inorg. Chim. Acta"},{"key":"tx2078_bb7","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1002\/ejic.201700920","author":"Pi\u00f1eiro-L\u00f3pez","year":"2018","journal-title":"Eur. J. Inorg. Chem."},{"key":"tx2078_bb8","doi-asserted-by":"crossref","first-page":"1317","DOI":"10.1039\/D0SC04420B","volume":"12","author":"Pi\u00f1eiro-L\u00f3pez","year":"2021","journal-title":"Chem. Sci."},{"key":"tx2078_bb15","unstructured":"Rigaku OD (2020). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England."},{"key":"tx2078_bb9","doi-asserted-by":"crossref","first-page":"3183","DOI":"10.1039\/B702574B","author":"Seredyuk","year":"2007","journal-title":"Dalton Trans."},{"key":"tx2078_bb10","doi-asserted-by":"crossref","first-page":"7424","DOI":"10.1021\/acs.inorgchem.5b01001","volume":"54","author":"Seredyuk","year":"2015","journal-title":"Inorg. Chem."},{"key":"tx2078_bb11","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"tx2078_bb12","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"tx2078_bb13","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."},{"key":"tx2078_bb14","doi-asserted-by":"crossref","first-page":"1611","DOI":"10.1039\/C3NJ01541F","volume":"38","author":"\u015awitlicka-Olszewska","year":"2014","journal-title":"New J. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2023\/12\/00\/tx2078\/tx2078.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2023\/12\/00\/tx2078\/tx2078.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T05:23:46Z","timestamp":1736745826000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989023009751"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,14]]},"references-count":15,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2023,12]]}},"alternative-id":["S2056989023009751"],"URL":"https:\/\/doi.org\/10.1107\/s2056989023009751","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989023009751\/tx2078sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989023009751\/tx2078Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989023009751\/tx2078Isup3.cdx","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,14]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?tx2078","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"30 October 2023","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"8 November 2023","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"14 November 2023","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?tx2078"}},{"value":"\u00a9 2023 Kuzevanova\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}