{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:28:26Z","timestamp":1785403706679,"version":"3.56.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2023,11,30]],"date-time":"2023-11-30T00:00:00Z","timestamp":1701302400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,11,30]],"date-time":"2023-11-30T00:00:00Z","timestamp":1701302400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["22BF037-04"],"award-info":[{"award-number":["22BF037-04"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,11,20]]},"published-print":{"date-parts":[[2023,12,1]]},"abstract":"<jats:p>\n                    The tetrakis complex of neodymium(III), tetrakis{\u03bc-\n                    <jats:italic>N<\/jats:italic>\n                    -[bis(pyrrolidin-1-yl)phosphoryl]acetamidato}bis(propan-2-ol)neodymiumsodium propan-2-ol monosolvate, [NaNd(C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>16<\/jats:sub>\n                    Cl\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    O or NaNdPyr\n                    <jats:sub>4<\/jats:sub>\n                    (\n                    <jats:italic>i<\/jats:italic>\n                    -PrOH)\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7\n                    <jats:italic>i<\/jats:italic>\n                    -PrOH, with the amide type CAPh ligand bis(\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    -tetramethylene)(trichloroacetyl)phosphoric acid triamide (HPyr), has been synthesized, crystallized and characterized by X-ray diffraction. The complex does not have the tetrakis(CAPh)lanthanide anion, which is typical for ester-type CAPh-based coordination compounds. Instead, the NdO\n                    <jats:sub>8<\/jats:sub>\n                    polyhedron is formed by one oxygen atom of a 2-propanol molecule and seven oxygen atoms of CAPh ligands in the title compound. Three CAPh ligands are coordinated in a bidentate chelating manner to the Nd\n                    <jats:sup>III<\/jats:sup>\n                    ion and simultaneously binding the sodium cation by \u03bc\n                    <jats:sub>2<\/jats:sub>\n                    -bridging PO and CO groups while the fourth CAPh ligand is coordinated to the sodium cation in a bidentate chelating manner and, due to the \u03bc\n                    <jats:sub>2<\/jats:sub>\n                    -bridging function of the PO group, also binds the neodymium ion.\n                  <\/jats:p>","DOI":"10.1107\/s2056989023010071","type":"journal-article","created":{"date-parts":[[2023,11,28]],"date-time":"2023-11-28T00:38:00Z","timestamp":1701131880000},"page":"1218-1222","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr\n                    <sub>4<\/sub>\n                    (\n                    <i>i<\/i>\n                    -PrOH)\n                    <sub>2<\/sub>\n                    \u00b7\n                    <i>i<\/i>\n                    -PrOH with a carbacylamidophosphate of the amide type"],"prefix":"10.1107","volume":"79","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8355-4938","authenticated-orcid":true,"given":"Nataliia S.","family":"Kariaka","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4613-172X","authenticated-orcid":true,"given":"Viktoriya V.","family":"Dyakonenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4818-8658","authenticated-orcid":true,"given":"Kateryna O.","family":"Znovjyak","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3946-1061","authenticated-orcid":true,"given":"Svitlana V.","family":"Shishkina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3499-267X","authenticated-orcid":true,"given":"Volodymyr M.","family":"Amirkhanov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,11,30]]},"reference":[{"key":"mw2199_bb1","unstructured":"Agilent (2014). 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