{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T18:56:20Z","timestamp":1785437780792,"version":"3.56.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2023,11,30]],"date-time":"2023-11-30T00:00:00Z","timestamp":1701302400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,11,30]],"date-time":"2023-11-30T00:00:00Z","timestamp":1701302400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Uzbekistan Ministry of Higher Education, Science and Innovation"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,11,22]]},"published-print":{"date-parts":[[2023,12,1]]},"abstract":"<jats:p>\n                    A novel\n                    <jats:italic>o<\/jats:italic>\n                    -phenylenediamine (opda)-based cadmium complex, bis(benzene-1,2-diamine-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032)bis(benzene-1,2-diamine-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    )cadmium(II) naphthalene-1,5-disulfonate, [Cd(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    ](C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    ), was synthesized. The complex salt crystallizes in the monoclinic space group\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>c<\/jats:italic>\n                    . The Cd atom occupies a special position and coordinates six nitrogen atoms from four\n                    <jats:italic>o<\/jats:italic>\n                    -phenylenediamine molecules, two as chelating ligands and two as monodentate ligands. The amino H atoms of opda interact with two O atoms of the naphthalene-1,5-disulfonate anions. The anions act as bridges between [Cd(opda)\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2+<\/jats:sup>\n                    cations, forming a two-dimensional network in the [010] and [001] directions. The Hirshfeld surface analysis shows that the primary factors contributing to the supramolecular interactions are short contacts, particularly van der Waals forces of the type H...H, O...H and C...H.\n                  <\/jats:p>","DOI":"10.1107\/s2056989023010125","type":"journal-article","created":{"date-parts":[[2023,11,23]],"date-time":"2023-11-23T10:19:11Z","timestamp":1700734751000},"page":"1190-1193","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of a cadmium complex of naphthalene-1,5-disulfonate and\n                    <i>o<\/i>\n                    -phenylenediamine"],"prefix":"10.1107","volume":"79","author":[{"given":"Jabbor","family":"Suyunov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9218-5596","authenticated-orcid":true,"given":"Batirbay","family":"Torambetov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khayit","family":"Turaev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0084-7653","authenticated-orcid":true,"given":"Shakhnoza","family":"Kadirova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bekmurod","family":"Alimnazarov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4441-2803","authenticated-orcid":true,"given":"Jamshid","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,11,30]]},"reference":[{"key":"dj2067_bb1","doi-asserted-by":"crossref","first-page":"m187","DOI":"10.1107\/S1600536804033574","volume":"61","author":"Ariyananda","year":"2005","journal-title":"Acta Cryst. 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