{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T20:33:43Z","timestamp":1790022823915,"version":"4.0.1"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2023,12,14]]},"published-print":{"date-parts":[[2024,1,1]]},"abstract":"<jats:p>The title compound, [Co(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or Co(NCS)<jats:sub>2<\/jats:sub>(2-methylpyridine <jats:italic>N<\/jats:italic>-oxide), was prepared by the reaction of Co(NCS)<jats:sub>2<\/jats:sub> and 2-methylpyridine <jats:italic>N<\/jats:italic>-oxide in methanol. All crystals obtained by this procedure show reticular pseudo-merohedric twinning, but after recrystallization, one crystal was found that had a minor component with only a very few overlapping reflections. The asymmetric unit consists of one Co<jats:sup>II<\/jats:sup> cation, two thiocyanate anions and one 2-methylpyridine <jats:italic>N<\/jats:italic>-oxide coligand in general positions. The Co<jats:sup>II<\/jats:sup> cations are octahedrally coordinated by two O-bonding 2-methylpyridine <jats:italic>N<\/jats:italic>-oxide ligands, as well as two S- and two N-bonding thiocyanate anions, and are connected <jats:italic>via<\/jats:italic> \u03bc-1,3(<jats:italic>N<\/jats:italic>,<jats:italic>S<\/jats:italic>)-bridging thiocyanate anions into chains that are linked by \u03bc-1,1(<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>) bridging coligands into layers. No pronounced directional intermolecular interactions are observed between the layers. The 2-methylpyridine coligand is disordered over two orientations and was refined using a split model with restraints. Powder X-ray diffraction (PXRD) indicates that a pure sample was obtained and IR spectroscopy confirms that bridging thiocyanate anions are present. Thermogravimetry and differential thermoanalysis (TG-DTA) shows one poorly resolved mass loss in the TG curve that is accompanied by an exothermic and an endothermic signal in the DTA curve, which indicate the decomposition of the 2-methylpyridine <jats:italic>N<\/jats:italic>-oxide coligands.<\/jats:p>","DOI":"10.1107\/s2056989023010721","type":"journal-article","created":{"date-parts":[[2023,12,22]],"date-time":"2023-12-22T09:42:42Z","timestamp":1703238162000},"page":"67-71","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis, crystal structure and properties of poly[(\u03bc-2-methylpyridine <i>N<\/i>-oxide-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>)bis(\u03bc-thiocyanato-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>:<i>S<\/i>)cobalt(II)]"],"prefix":"10.1107","volume":"80","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,1,1]]},"reference":[{"key":"pk2699_bb1","doi-asserted-by":"crossref","first-page":"3547","DOI":"10.1039\/c0ce00149j","volume":"12","author":"Adams","year":"2010","journal-title":"CrystEngComm"},{"key":"pk2699_bb2","doi-asserted-by":"crossref","first-page":"5325","DOI":"10.1021\/acs.inorgchem.9b03357","volume":"59","author":"B\u00f6hme","year":"2020","journal-title":"Inorg. 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