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The metal ion in <jats:bold>I<\/jats:bold> possesses a pentagonal\u2013bipyramidal environment with the four O atoms of the two bidentately coordinated carboxylate groups and the N atom of a pyridine molecule forming the O<jats:sub>4<\/jats:sub>N equatorial plane, while the N atom of another pyridine ligand and the O atom of the water molecule occupy the axial positions. The bct<jats:sup>2\u2013<\/jats:sup> bridging ligand connects two metal ions <jats:italic>via<\/jats:italic> its carboxylic groups, resulting in the formation of a parallel linear polymeric chain running along the [1\\overline{1}1] direction. The coordinated water molecule of one chain forms a strong O\u2014H...O hydrogen bond with the carboxylate O atom of a neighboring chain, leading to the formation of double chains with a closest distance of 5.425\u2005(7)\u2005\u00c5 between the cadmium ions belonging to different chains. Aromatic \u03c0\u2013\u03c0 stacking interactions between the benzene fragments of the anions as well as between the coordinated pyridine molecules belonging to different chains results in the formation of sheets oriented parallel to the (\\overline{1}01) plane. As a result of hydrogen-bonding interactions involving the water molecules of crystallization, the sheets are joined together in a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989024000185","type":"journal-article","created":{"date-parts":[[2024,1,9]],"date-time":"2024-01-09T08:54:12Z","timestamp":1704790452000},"page":"128-132","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of a cadmium(II) coordination polymer based on 4,4\u2032-(1<i>H<\/i>-1,2,4-triazole-3,5-diyl)dibenzoate"],"prefix":"10.1107","volume":"80","author":[{"given":"Anastasiia M.","family":"Popovych","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liudmyla V.","family":"Tsymbal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7058-832X","authenticated-orcid":true,"given":"Dmytro M.","family":"Khomenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9433-9595","authenticated-orcid":true,"given":"Alexandra","family":"Bargan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8326-4535","authenticated-orcid":true,"given":"Rostislav D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,1,9]]},"reference":[{"key":"hb8090_bb1","doi-asserted-by":"crossref","first-page":"2612","DOI":"10.1016\/j.poly.2007.01.005","volume":"26","author":"Bania","year":"2007","journal-title":"Polyhedron"},{"key":"hb8090_bb2","doi-asserted-by":"crossref","first-page":"16811","DOI":"10.1039\/C4TA02984D","volume":"2","author":"Chen","year":"2014","journal-title":"J. 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