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It crystallizes as a centrosymmetric dimer, with one cadmium atom, two bromine atoms and one <jats:italic>N<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>-bidentate 4-(2-aminoethyl)morpholine ligand in the asymmetric unit. The metal atom is six-coordinated and has a distorted octahedral geometry. In the crystal, O...Cd interactions link the dimers into a polymeric double chain and intermolecular C\u2014H...O hydrogen bonds form <jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>\n                  <jats:sup>2<\/jats:sup>(6) ring motifs. Further C\u2014H...Br and N\u2014H...Br hydrogen bonds link the components into a three-dimensional network. As the N\u2014H...Br hydrogen bonds are shorter than the C\u2014H...Br interactions, they have a larger effect on the packing. 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