{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:21:14Z","timestamp":1736832074377,"version":"3.33.0"},"reference-count":35,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T00:00:00Z","timestamp":1713398400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T00:00:00Z","timestamp":1713398400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,4,10]]},"published-print":{"date-parts":[[2024,5,1]]},"abstract":"<jats:p>Reaction of Co(NCS)<jats:sub>2<\/jats:sub> with 4-methylpyridine <jats:italic>N<\/jats:italic>-oxide in methanol leads to the formation of crystals of the title compound, [Co<jats:sub>2<\/jats:sub>(NCS)<jats:sub>4<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)<jats:sub>4<\/jats:sub>(CH<jats:sub>4<\/jats:sub>O)<jats:sub>2<\/jats:sub>] or Co<jats:sub>2<\/jats:sub>(NCS)<jats:sub>4<\/jats:sub>(4-methylpyridine <jats:italic>N<\/jats:italic>-oxide)<jats:sub>4<\/jats:sub>(methanol)<jats:sub>2<\/jats:sub>. The asymmetric unit consist of one Co<jats:sup>II<\/jats:sup> cation, two thiocyanate anions, two 4-methylpyridine <jats:italic>N<\/jats:italic>-oxide coligands and one methanol molecule in general positions. The H atoms of one of the methyl groups are disordered and were refined using a split model. The Co<jats:sup>II<\/jats:sup> cations octahedrally coordinate two terminal N-bonded thiocyanate anions, three 4-methylpyridine <jats:italic>N<\/jats:italic>-oxide coligands and one methanol molecule. Each two Co<jats:sup>II<\/jats:sup> cations are linked by pairs of \u03bc-1,1(<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>)-bridging 4-methylpyridine <jats:italic>N<\/jats:italic>-oxide coligands into dinuclear units that are located on centers of inversion. Powder X-ray diffraction (PXRD) investigations prove that the title compound is contaminated with a small amount of Co(NCS)<jats:sub>2<\/jats:sub>(4-methylpyridine <jats:italic>N<\/jats:italic>-oxide)<jats:sub>3<\/jats:sub>. Thermogravimetric investigations reveal that the methanol molecules are removed in the beginning, leading to a compound with the composition Co(NCS)<jats:sub>2<\/jats:sub>(4-methylpyridine <jats:italic>N<\/jats:italic>-oxide), which has been reported in the literature and which is of poor crystallinity.<\/jats:p>","DOI":"10.1107\/s2056989024003128","type":"journal-article","created":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T14:09:46Z","timestamp":1713449386000},"page":"481-485","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis, crystal structure and thermal properties of the dinuclear complex bis(\u03bc-4-methylpyridine <i>N<\/i>-oxide-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>)bis[(methanol-\u03ba<i>O<\/i>)(4-methylpyridine <i>N<\/i>-oxide-\u03ba<i>O<\/i>)bis(thiocyanato-\u03ba<i>N<\/i>)cobalt(II)]"],"prefix":"10.1107","volume":"80","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,4,18]]},"reference":[{"key":"jp2005_bb1","doi-asserted-by":"crossref","first-page":"5325","DOI":"10.1021\/acs.inorgchem.9b03357","volume":"59","author":"B\u00f6hme","year":"2020","journal-title":"Inorg. 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