{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:21:15Z","timestamp":1736832075769,"version":"3.33.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T00:00:00Z","timestamp":1714089600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T00:00:00Z","timestamp":1714089600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,4,15]]},"published-print":{"date-parts":[[2024,5,1]]},"abstract":"<jats:p>Di-\u03bc-hydroxido-bis[dibromido(dimethylformamide-\u03ba<jats:italic>O<\/jats:italic>)ethyltin(IV)], [Sn<jats:sub>2<\/jats:sub>Br<jats:sub>4<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)<jats:sub>2<\/jats:sub>], was prepared from ethyltin(IV) bromide and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylformamide (DMF) in air. The crystal structure exhibits the typical structural features of dimeric Lewis-base-stabilized monoorganotin(IV)\u2013dihalide\u2013hydroxides, <jats:italic>R<\/jats:italic>SnHal<jats:sub>2<\/jats:sub>(OH), <jats:italic>i.e.<\/jats:italic> two octahedrally coordinated Sn atoms are linked together <jats:italic>via<\/jats:italic> two bridging hydroxide groups, resulting in a centrosymmetric four-membered rhomboid-like Sn\u2013OH ring with acute angles at the Sn atom, obtuse angles at the O atoms and two different tin\u2013oxygen bond lengths. With the shorter bond <jats:italic>trans<\/jats:italic> to the ethyl group, this observation underlines once more the so-called <jats:italic>trans-strengthening<\/jats:italic> effect in monoorganotin(IV) compounds with octahedrally coordinated Sn atoms. Differences and similarities in the bond lengths and angles in the four-membered Sn\u2013OH rings have been worked out for the rings in dimeric diorganotin(IV)\u2013halide\u2013hydroxides, [<jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>SnHal(OH)]<jats:sub>2<\/jats:sub>, and hydrates of dimeric tin(IV)\u2013trihalide\u2013hydroxide\u2013aqua\u2013hydrates, [SnHal<jats:sub>3<\/jats:sub>(OH)(H<jats:sub>2<\/jats:sub>O)]<jats:sub>2<\/jats:sub>\u00b7<jats:italic>n<\/jats:italic>H<jats:sub>2<\/jats:sub>O.<\/jats:p>","DOI":"10.1107\/s2056989024003268","type":"journal-article","created":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T07:48:18Z","timestamp":1714117698000},"page":"522-526","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Dimeric ethyltin(IV)\u2013dibromide\u2013hydroxide\u2013<i>N<\/i>,<i>N<\/i>-dimethylformamide"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7878-5520","authenticated-orcid":true,"given":"Christopher Jan","family":"Klecker","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1251-0783","authenticated-orcid":true,"given":"Hans","family":"Reuter","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,4,26]]},"reference":[{"key":"yy2010_bb1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1039\/p298700000s1","volume":"2","author":"Allen","year":"1987","journal-title":"J. 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