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The complex, of general formula C<jats:sub>84<\/jats:sub>H<jats:sub>80<\/jats:sub>N<jats:sub>8<\/jats:sub>O<jats:sub>8<\/jats:sub>\u00b72C<jats:sub>7<\/jats:sub>H<jats:sub>5<\/jats:sub>N, crystallizes in the space group <jats:italic>P<\/jats:italic>\\overline{1} with two independent molecules in the asymmetric unit, displaying very similar geometrical parameters. For each complex, one of the benzonitrile molecules is engulfed inside the cavity, while the other is located among the alkyl legs at the lower rim. The host and the guests mainly interact through weak C\u2014H...\u03c0, C\u2014H...N and dispersion interactions. These interactions help to consolidate the formation of supramolecular chains running along the crystallographic <jats:italic>b-<\/jats:italic>axis direction.<\/jats:p>","DOI":"10.1107\/s205698902400481x","type":"journal-article","created":{"date-parts":[[2024,5,31]],"date-time":"2024-05-31T08:22:53Z","timestamp":1717143773000},"page":"671-676","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Structural characterization of the supramolecular complex between a tetraquinoxaline-based cavitand and benzonitrile"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0000-8980","authenticated-orcid":true,"given":"Roberta","family":"Pinalli","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chiara","family":"Massera","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,5,31]]},"reference":[{"key":"jw2007_bb1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1107\/S0021889804003528","volume":"37","author":"Allen","year":"2004","journal-title":"J. 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