{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:23:07Z","timestamp":1785403387886,"version":"3.56.0"},"reference-count":51,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2024,8,20]],"date-time":"2024-08-20T00:00:00Z","timestamp":1724112000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,8,20]],"date-time":"2024-08-20T00:00:00Z","timestamp":1724112000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,8,12]]},"published-print":{"date-parts":[[2024,9,1]]},"abstract":"<jats:p>\n                    The present study focuses on the synthesis and structural characterization of a novel dinuclear Cu\n                    <jats:sup>II<\/jats:sup>\n                    complex, [trichloridocopper(II)]-\u03bc-chlorido-{bis[2-hydroxy-\n                    <jats:italic>N<\/jats:italic>\n                    \u2032-(propan-2-ylidene)benzohydrazide]copper(II)} monohydrate, [Cu\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>4<\/jats:sub>\n                    (C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O or [Cu(H\n                    <jats:sub>2<\/jats:sub>\n                    <jats:italic>L<\/jats:italic>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc-Cl)CuCl\n                    <jats:sub>3<\/jats:sub>\n                    ]\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O [H\n                    <jats:sub>2<\/jats:sub>\n                    <jats:italic>L<\/jats:italic>\n                    = 2-hydroxy-\n                    <jats:italic>N<\/jats:italic>\n                    \u2032-(propan-2-ylidene)benzohydrazide]. The complex crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    with one molecule of water, which forms interactions with the ligands. The first copper ion is penta-coordinated to two benzohydrazine-derived ligands\n                    <jats:italic>via<\/jats:italic>\n                    two nitrogen and two oxygen atoms, and one bridging chloride, which is also coordinated by the second copper ion alongside three terminal chlorines in a distorted tetrahedral geometry. The arrangement around the first copper ion exhibits a distorted geometry intermediate between trigonal bipyramidal and square pyramidal. In the crystal, chains are formed\n                    <jats:italic>via<\/jats:italic>\n                    intermolecular interactions along the\n                    <jats:italic>a-<\/jats:italic>\n                    axis direction, with subsequent layers constructed through hydrogen-bonding interactions parallel to the\n                    <jats:italic>ac<\/jats:italic>\n                    plane, and through slipped \u03c0\u2013\u03c0 stacking interactions parallel to the\n                    <jats:italic>ab<\/jats:italic>\n                    plane, resulting in a three-dimensional network. The intermolecular interactions in the crystal structure were quantified and analysed using Hirshfeld surface analysis. Residual electron density from disordered methanol molecules in the void space could not be reasonably modelled, thus a solvent mask was applied.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024007941","type":"journal-article","created":{"date-parts":[[2024,8,15]],"date-time":"2024-08-15T10:37:15Z","timestamp":1723718235000},"page":"961-966","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of [Cu(H\n                    <sub>2<\/sub>\n                    <i>L<\/i>\n                    )\n                    <sub>2<\/sub>\n                    (\u03bc-Cl)CuCl\n                    <sub>3<\/sub>\n                    ]\u00b7H\n                    <sub>2<\/sub>\n                    O [H\n                    <sub>2<\/sub>\n                    <i>L<\/i>\n                    = 2-hydroxy-\n                    <i>N<\/i>\n                    \u2032-(propan-2-ylidene)benzohydrazide]"],"prefix":"10.1107","volume":"80","author":[{"given":"Imededdine","family":"Boulguemh","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wv6808","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4773-0003","authenticated-orcid":true,"given":"Asma","family":"Lehleh","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wv6808","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chahrazed","family":"Beghidja","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wv6808","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9740-8787","authenticated-orcid":true,"given":"Adel","family":"Beghidja","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wv6808","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,8,20]]},"reference":[{"key":"ev2007_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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