{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T18:58:54Z","timestamp":1785437934495,"version":"3.56.0"},"reference-count":54,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T00:00:00Z","timestamp":1727654400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T00:00:00Z","timestamp":1727654400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100007260","name":"State University of New York at New Paltz","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007260","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,9,11]]},"published-print":{"date-parts":[[2024,10,1]]},"abstract":"<jats:p>\n                    When reacted in dry, degassed toluene, [Ir(COD)Cl]\n                    <jats:sub>2<\/jats:sub>\n                    (COD = cycloocta-1,5-diene) and 2 equivalents of 2-(di-\n                    <jats:italic>tert<\/jats:italic>\n                    -butylphosphinito)anthraquinone (\n                    <jats:sup>tBu<\/jats:sup>\n                    POAQH) were found to form a unique tri-iridium compound consisting of one monoanionic dinuclear tri-\u03bc-chlorido complex bearing one bidentate\n                    <jats:sup>tBu<\/jats:sup>\n                    POAQ ligand per iridium, which was charge-balanced by an outer sphere [Ir(toluene)(COD)]\n                    <jats:sup>+<\/jats:sup>\n                    ion, the structure of which has not previously been reported. This product, which is a toluene solvate, namely, (\u03b7\n                    <jats:sup>2<\/jats:sup>\n                    :\u03b7\n                    <jats:sup>2<\/jats:sup>\n                    -cycloocta-1,5-diene)(\u03b7\n                    <jats:sup>6<\/jats:sup>\n                    -toluene)iridium(I) tri-\u03bc-chlorido-bis({3-[(di-\n                    <jats:italic>tert<\/jats:italic>\n                    -butylphosphanyl)oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(III)) toluene monosolvate, [Ir(C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    )(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    )][Ir\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>24<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>3<\/jats:sub>\n                    ]\u00b7C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    or [Ir(toluene)(COD)][Ir(\u03ba-\n                    <jats:italic>P<\/jats:italic>\n                    ,\n                    <jats:italic>C<\/jats:italic>\n                    -\n                    <jats:sup>tBu<\/jats:sup>\n                    POAQ)(H)]\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc-Cl)\n                    <jats:sub>3<\/jats:sub>\n                    ]\u00b7toluene, formed as small orange platelets at room temperature, crystallizing in the triclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    \\overline{1}. The cation and anion are linked\n                    <jats:italic>via<\/jats:italic>\n                    weak C\u2014H...O interactions. The stronger intermolecular attractions are likely the offset parallel \u03c0\u2013\u03c0 interactions, which occur between the toluene ligands of pairs of inverted cations and between pairs of inverted anthraquinone moieties, the latter of which are capped by toluene solvate molecules, making for \u03c0-stacks of four molecules each. The related ligand, 2-(di-\n                    <jats:italic>tert<\/jats:italic>\n                    -butylphosphinomethyl)-anthraquinone (\n                    <jats:sup>tBu<\/jats:sup>\n                    PCAQH), did not form crystals suitable for X-ray diffraction under analogous reaction conditions. However, when the reaction was conducted in chloroform, yellow needles readily formed following addition of 1 atm of carbon monoxide. Diffraction studies revealed a neutral, dinuclear, di-\u03bc-chlorido complex, di-\u03bc-chlorido-bis(carbonyl{3-[(di-\n                    <jats:italic>tert<\/jats:italic>\n                    -butylphosphanyl)oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(I)), [Ir\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>23<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    (CO)\n                    <jats:sub>2<\/jats:sub>\n                    ] or [Ir(\u03ba-\n                    <jats:italic>P<\/jats:italic>\n                    ,\n                    <jats:italic>C<\/jats:italic>\n                    -\n                    <jats:sup>tBu<\/jats:sup>\n                    PCAQ)(H)(CO)(\u03bc-Cl)]\n                    <jats:sub>2<\/jats:sub>\n                    , Ir\n                    <jats:sub>2<\/jats:sub>\n                    C\n                    <jats:sub>48<\/jats:sub>\n                    H\n                    <jats:sub>54<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    , again crystallizing in space group\n                    <jats:italic>P<\/jats:italic>\n                    \\overline{1}. Offset parallel \u03c0\u2013\u03c0 interactions between anthraquinone groups of adjacent molecules link the molecules in one dimension.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024008922","type":"journal-article","created":{"date-parts":[[2024,9,26]],"date-time":"2024-09-26T01:38:42Z","timestamp":1727314722000},"page":"1101-1109","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of the (\u03b7\n                    <sup>2<\/sup>\n                    :\u03b7\n                    <sup>2<\/sup>\n                    -cycloocta-1,5-diene)(\u03b7\n                    <sup>6<\/sup>\n                    -toluene)iridium(I) cation and \u03bc-chlorido-iridium(III) complexes of 2-(phosphinito)- and 2-(phosphinomethyl)anthraquinone ligands"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-1056-2360","authenticated-orcid":true,"given":"Sachin","family":"Thackeray","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q1z8k08","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James","family":"Mahoney","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q1z8k08","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ashleigh","family":"Arrington","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q1z8k08","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2678-8700","authenticated-orcid":true,"given":"Miles","family":"Wilklow-Marnell","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01q1z8k08","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5461-1825","authenticated-orcid":true,"given":"William W.","family":"Brennessel","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/022kthw22","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,9,30]]},"reference":[{"key":"jy2049_bb1","doi-asserted-by":"crossref","first-page":"6610","DOI":"10.1039\/b904938j","author":"Aguil\u00e0","year":"2009","journal-title":"Dalton Trans."},{"key":"jy2049_bb2","doi-asserted-by":"crossref","first-page":"3750","DOI":"10.1002\/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6","volume":"40","author":"Albrecht","year":"2001","journal-title":"Angew. 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