{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,10,10]],"date-time":"2024-10-10T04:13:52Z","timestamp":1728533632197},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2024,9,24]],"date-time":"2024-09-24T00:00:00Z","timestamp":1727136000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,9,24]],"date-time":"2024-09-24T00:00:00Z","timestamp":1727136000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,9,19]]},"published-print":{"date-parts":[[2024,10,1]]},"abstract":"<jats:p>Reaction of copper(I)chloride with 2,3-dimethylpyrazine in ethanol leads to the formation of the title compound, poly[[\u03bc-chlorido-\u03bc-(2,3-dimethylpyrazine)-copper(I)] ethanol hemisolvate], {[CuCl(C<jats:sub>6<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)]\u00b70.5C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub>OH}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or CuCl(2,3-dimethylpyrazine) ethanol hemisolvate. Its asymmetric unit consists of two crystallographically independent copper cations, two chloride anions and two 2,3-dimethylpyrazine ligands as well as one ethanol solvate molecule in general positions. The ethanol molecule is disordered and was refined using a split model. The methyl H atoms of the 2,3-dimethylpyrazine ligands are also disordered and were refined in two orientations rotated by 60\u00b0 relative to each other. In the crystal structure, each copper cation is tetrahedrally coordinated by two N atoms of two bridging 2,3-dimethylpyrazine ligands and two \u03bc-1,1-bridging chloride anions. Each of the two copper cations are linked by pairs of bridging chloride anions into dinuclear units that are further linked into layers <jats:italic>via<\/jats:italic> bridging 2,3-dimethylpyrazine coligands. These layers are stacked in such a way that channels are formed in which the disordered solvent molecules are located. The topology of this network is completely different from that observed in the two polymorphic modifications of CuCl(2,3-dimethylpyrazine) reported in the literature [Jess &amp; N\u00e4ther (2006). <jats:italic>Inorg. Chem.<\/jats:italic> \n                  <jats:bold>45<\/jats:bold>, 7446\u20137454]. Powder X-ray diffraction measurements reveal that the title compound is unstable and transforms immediately into an unknown crystalline phase.<\/jats:p>","DOI":"10.1107\/s2056989024009174","type":"journal-article","created":{"date-parts":[[2024,9,24]],"date-time":"2024-09-24T07:27:27Z","timestamp":1727162847000},"page":"1059-1063","update-policy":"http:\/\/dx.doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of poly[[\u03bc-chlorido-\u03bc-(2,3-dimethylpyrazine)-copper(I)] ethanol hemisolvate], which shows a new isomeric CuCl(2,3-dimethylpyrazine) network"],"prefix":"10.1107","volume":"80","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,9,24]]},"reference":[{"key":"nx2014_bb1","unstructured":"Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"nx2014_bb2","doi-asserted-by":"crossref","first-page":"12809","DOI":"10.1021\/acs.inorgchem.7b01562","volume":"56","author":"Gibbons","year":"2017","journal-title":"Inorg. Chem."},{"key":"nx2014_bb3","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"nx2014_bb4","doi-asserted-by":"crossref","first-page":"2263","DOI":"10.1039\/B701905J","author":"Jess","year":"2007","journal-title":"Dalton Trans."},{"key":"nx2014_bb5","doi-asserted-by":"crossref","first-page":"7446","DOI":"10.1021\/ic060747b","volume":"45","author":"Jess","year":"2006","journal-title":"Inorg. Chem."},{"key":"nx2014_bb6","doi-asserted-by":"crossref","first-page":"617","DOI":"10.1515\/znb-2007-0424","volume":"62","author":"Jess","year":"2007","journal-title":"Z. Naturforsch. B"},{"key":"nx2014_bb7","doi-asserted-by":"crossref","first-page":"501","DOI":"10.1515\/znb-2007-0403","volume":"62","author":"Jess","year":"2007","journal-title":"Z. Naturforsch. B"},{"key":"nx2014_bb8","doi-asserted-by":"crossref","first-page":"6315","DOI":"10.1021\/ic3005147","volume":"51","author":"Jornet-Somoza","year":"2012","journal-title":"Inorg. Chem."},{"key":"nx2014_bb9","doi-asserted-by":"crossref","first-page":"1175","DOI":"10.1515\/znb-1999-0914","volume":"54","author":"Kromp","year":"1999","journal-title":"Z. Naturforsch. B"},{"key":"nx2014_bb10","doi-asserted-by":"crossref","first-page":"3907","DOI":"10.1021\/ic050209j","volume":"44","author":"Li","year":"2005","journal-title":"Inorg. Chem."},{"key":"nx2014_bb11","doi-asserted-by":"crossref","first-page":"816363","DOI":"10.3389\/fchem.2021.816363","volume":"9","author":"Mensah","year":"2022","journal-title":"Front. Chem."},{"key":"nx2014_bb12","doi-asserted-by":"crossref","first-page":"377","DOI":"10.1107\/S0108270101000051","volume":"57","author":"N\u00e4ther","year":"2001","journal-title":"Acta Cryst. C"},{"key":"nx2014_bb13","doi-asserted-by":"crossref","first-page":"813","DOI":"10.1016\/S1293-2558(02)01326-2","volume":"4","author":"N\u00e4ther","year":"2002","journal-title":"Solid State Sci."},{"key":"nx2014_bb14","doi-asserted-by":"crossref","first-page":"1167","DOI":"10.1016\/S1293-2558(03)00128-6","volume":"5","author":"N\u00e4ther","year":"2003","journal-title":"Solid State Sci."},{"key":"nx2014_bb15","doi-asserted-by":"crossref","first-page":"2868","DOI":"10.1002\/ejic.200300950","volume":"2004","author":"N\u00e4ther","year":"2004","journal-title":"Eur. J. Inorg. Chem."},{"key":"nx2014_bb16","doi-asserted-by":"crossref","first-page":"1017","DOI":"10.1016\/S0277-5387(01)00723-9","volume":"20","author":"N\u00e4ther","year":"2001","journal-title":"Polyhedron"},{"key":"nx2014_bb17","doi-asserted-by":"crossref","first-page":"897","DOI":"10.1007\/s007060170053","volume":"132","author":"N\u00e4ther","year":"2001","journal-title":"Monatsh. Chem."},{"key":"nx2014_bb18","doi-asserted-by":"crossref","first-page":"2696","DOI":"10.1002\/zaac.201300274","volume":"639","author":"N\u00e4ther","year":"2013","journal-title":"Z. Anorg. Allg. Chem."},{"key":"nx2014_bb19","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ccr.2009.10.003","volume":"254","author":"Peng","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"nx2014_bb20","doi-asserted-by":"crossref","first-page":"861","DOI":"10.1039\/c0nj00809e","volume":"35","author":"Posp\u00ed\u0161il","year":"2011","journal-title":"New J. Chem."},{"key":"nx2014_bb21","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"nx2014_bb29","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"nx2014_bb22","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"nx2014_bb23","unstructured":"Stoe (2008). X-AREA, X-RED32 and X-SHAPE. Stoe & Cie, Darmstadt, Germany."},{"key":"nx2014_bb24","unstructured":"Turnbull, M. M., Butcher, R. T. & Robinson, W. T. (2020). CSD Communication (CCDC 1994875). CCDC, Cambridge, England."},{"key":"nx2014_bb25","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.molcata.2004.09.068","volume":"228","author":"Wells","year":"2005","journal-title":"J. Mol. Catal. A Chem."},{"key":"nx2014_bb26","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"nx2014_bb27","first-page":"396","volume":"26","author":"Xiao","year":"2010","journal-title":"J. Mol. Sci."},{"key":"nx2014_bb28","doi-asserted-by":"crossref","first-page":"14103","DOI":"10.1039\/D0NJ02341H","volume":"44","author":"Xu","year":"2020","journal-title":"New J. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2024\/10\/00\/nx2014\/nx2014.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2024\/10\/00\/nx2014\/nx2014.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,10,9]],"date-time":"2024-10-09T05:02:40Z","timestamp":1728450160000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989024009174"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,9,24]]},"references-count":29,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2024,10]]}},"alternative-id":["S2056989024009174"],"URL":"https:\/\/doi.org\/10.1107\/s2056989024009174","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989024009174\/nx2014sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989024009174\/nx2014Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989024009174\/nx2014sup3.png","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2024,9,24]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?nx2014","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"17 September 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 September 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 September 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?nx2014"}},{"value":"\u00a9 2024 N\u00e4ther and Jess","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}