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The Cd<jats:sup>2+<\/jats:sup> complex crystallizes in <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic> with a distorted trigonal\u2013bipyramidal metal coordination geometry. Supramolecular interactions in <jats:bold>1<\/jats:bold> include parallel offset face-to-face interactions between inversion-related pyridyl rings and potential hydrogen bonds with chlorine or sulfur as the acceptor. Additional cooperative pyridyl\u2013pyridyl interactions with roughly 45\u00b0 tilt angles and centroid\u2013centroid distances of less than 5.5\u2005\u00c5 likely also contribute to the overall solid-state stability. Hirshfeld surface analysis indicates that H...H (51.2%), Cl...H\/H...Cl (13.9%), C...H\/H...C (12.3%) and S...H\/H...S (11.8%) interactions are dominant in the solid state.<\/jats:p>","DOI":"10.1107\/s2056989024009198","type":"journal-article","created":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T09:53:37Z","timestamp":1727690017000},"page":"1081-1086","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of {2-[bis(pyridin-2-ylmethyl)amino]ethane-1-thiolato}chloridocadmium(II)"],"prefix":"10.1107","volume":"80","author":[{"given":"Todd M.","family":"Reynolds","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Steven M.","family":"Berry","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9228-6218","authenticated-orcid":true,"given":"Deborah C.","family":"Bebout","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,9,30]]},"reference":[{"key":"yz2058_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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