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The asymmetric unit consists of two crystallographically independent [SbS<jats:sub>4<\/jats:sub>]<jats:sup>3\u2013<\/jats:sup> anions, two independent perchlorate anions and two independent water molecules as well as four crystallographically independent Zn(cyclam)<jats:sup>2+<\/jats:sup> cations that are located in general positions. Both perchlorate anions and one cyclam ligand are disordered and were refined with a split mode using restraints. The water molecules are partially occupied. Two Zn(cyclam)<jats:sup>2+<\/jats:sup> cations are linked <jats:italic>via<\/jats:italic> the [SbS<jats:sub>4<\/jats:sub>]<jats:sup>3\u2013<\/jats:sup> anions into [Zn<jats:sub>2<\/jats:sub>(cyclam)<jats:sub>2<\/jats:sub>SbS<jats:sub>4<\/jats:sub>]<jats:sup>+<\/jats:sup> cations that are charged-balanced by the [ClO<jats:sub>4<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> anions. The water molecules of crystallization are hydrogen bonded to the [SbS<jats:sub>4<\/jats:sub>]<jats:sup>3\u2013<\/jats:sup> anions. The cations, anions and water molecules are linked by N\u2014H...O, N\u2014H...S and O\u2014H...S hydrogen bonds into a three-dimensional network. Powder X-ray diffraction proves that a pure sample had been obtained that was additionally investigated for its spectroscopic properties.<\/jats:p>","DOI":"10.1107\/s2056989024009356","type":"journal-article","created":{"date-parts":[[2024,9,25]],"date-time":"2024-09-25T07:07:20Z","timestamp":1727248040000},"page":"1151-1156","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and properties of \u03bc-tetrathioantimonato-bis[(cyclam)zinc(II)] perchlorate 0.8-hydrate"],"prefix":"10.1107","volume":"80","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Henning","family":"L\u00fchmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3111-580X","authenticated-orcid":true,"given":"Wolfgang","family":"Bensch","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,10,11]]},"reference":[{"key":"hb8108_bb1","doi-asserted-by":"crossref","first-page":"16953","DOI":"10.1002\/chem.201404396","volume":"20","author":"Anderer","year":"2014","journal-title":"Chem. 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