{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:15:15Z","timestamp":1785406515080,"version":"3.56.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2024,10,15]],"date-time":"2024-10-15T00:00:00Z","timestamp":1728950400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,10,15]],"date-time":"2024-10-15T00:00:00Z","timestamp":1728950400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,10,7]]},"published-print":{"date-parts":[[2024,11,1]]},"abstract":"<jats:p>\n                    The title compound, [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    ClN\n                    <jats:sub>4<\/jats:sub>\n                    O)Cl\n                    <jats:sub>3<\/jats:sub>\n                    ], is a dinuclear zinc(II) complex with three chlorido ligands and one pentadentate ligand containing quinolin-8-olato and bis(pyridin-2-ylmethyl)amine groups. One of the two Zn\n                    <jats:sup>II<\/jats:sup>\n                    atom adopts a tetrahedral geometry and coordinates two chlorido ligands with chelate coordination of the N and O atoms of the quinolin-8-olato group in the ligand. The other Zn\n                    <jats:sup>II<\/jats:sup>\n                    atom adopts a distorted trigonal\u2013bipyramidal geometry, and coordinates one chlorido-O atom of the quinolin-8-olato group and three N atoms of the bis(pyridin-2-ylmethyl)amine unit. In the crystal, two molecules are associated through a pair of intermolecular C\u2014H...Cl hydrogen bonds, forming a dimer with an\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>2<\/jats:sup>\n                    (12) ring motif. Another intermolecular C\u2014H...Cl hydrogen bond forms a spiral\n                    <jats:italic>C<\/jats:italic>\n                    (8) chain running parallel to the [010] direction. The dimers are linked by these two intermolecular C\u2014H...Cl hydrogen bonds, generating a ribbon sheet structure in\n                    <jats:italic>ac<\/jats:italic>\n                    plane. Two other intermolecular C\u2014H...Cl hydrogen bonds form a\n                    <jats:italic>C<\/jats:italic>\n                    (7) chain along the\n                    <jats:italic>c<\/jats:italic>\n                    -axis direction and another\n                    <jats:italic>C<\/jats:italic>\n                    (7) chain generated by a\n                    <jats:italic>d<\/jats:italic>\n                    -glide plane. The molecules are cross-linked through the four intermolecular C\u2014H...Cl hydrogen bonds to form a three-dimensional network.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024009782","type":"journal-article","created":{"date-parts":[[2024,10,9]],"date-time":"2024-10-09T04:56:32Z","timestamp":1728449792000},"page":"1175-1179","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of (\u03bc\n                    <sub>2<\/sub>\n                    -7-{[bis(pyridin-2-ylmethyl)amino-1\u03ba\n                    <sup>3<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032,\n                    <i>N<\/i>\n                    \u2032\u2032]methyl}-5-chloroquinolin-8-olato-2\u03ba\n                    <i>N<\/i>\n                    ;1:2\u03ba\n                    <sup>2<\/sup>\n                    <i>O<\/i>\n                    )trichlorido-1\u03ba\n                    <i>Cl<\/i>\n                    ,2\u03ba\n                    <sup>2<\/sup>\n                    <i>Cl<\/i>\n                    -dizinc(II)"],"prefix":"10.1107","volume":"80","author":[{"given":"Koji","family":"Kubono","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kanata","family":"Tanaka","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keita","family":"Tani","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4122-3345","authenticated-orcid":true,"given":"Yukiyasu","family":"Kashiwagi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,10,15]]},"reference":[{"key":"jp2012_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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