{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:29:57Z","timestamp":1785432597247,"version":"3.56.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,10,10]]},"published-print":{"date-parts":[[2024,11,1]]},"abstract":"\n The asymmetric unit of the title compound, [Co(C\n 8<\/jats:sub>\n Br\n 4<\/jats:sub>\n O\n 4<\/jats:sub>\n )(C\n 3<\/jats:sub>\n H\n 4<\/jats:sub>\n N\n 2<\/jats:sub>\n )\n 2<\/jats:sub>\n (H\n 2<\/jats:sub>\n O)\n 2<\/jats:sub>\n ]\n \n n<\/jats:italic>\n <\/jats:sub>\n or [Co(Br\n 4<\/jats:sub>\n bdc)(im)\n 2<\/jats:sub>\n (H\n 2<\/jats:sub>\n O)\n 2<\/jats:sub>\n ]\n \n n<\/jats:italic>\n <\/jats:sub>\n , comprises half of Co\n II<\/jats:sup>\n ion, tetrabromobenzenedicarboxylate (Br\n 4<\/jats:sub>\n bdc\n 2\u2212<\/jats:sup>\n ), imidazole (im) and a water molecule. The Co\n II<\/jats:sup>\n ion exhibits a six-coordinated octahedral geometry with two oxygen atoms of the Br\n 4<\/jats:sub>\n bdc\n 2\u2212<\/jats:sup>\n ligand, two oxygen atoms of the water molecules, and two nitrogen atoms of the im ligands. The carboxylate group is nearly perpendicular to the benzene ring and shows monodentate coordination to the Co\n II<\/jats:sup>\n ion. The Co\n II<\/jats:sup>\n ions are bridged by the Br\n 4<\/jats:sub>\n bdc\n 2\u2212<\/jats:sup>\n ligand, forming a one-dimensional chain. The carboxylate group acts as an intermolecular hydrogen-bond acceptor toward the im ligand and a coordinated water molecule. The chains are connected by interchain N\u2014H...O(carboxylate) and O\u2014H(water)...O(carboxylate) hydrogen-bonding interactions and are not arranged in parallel but cross each other\n via<\/jats:italic>\n interchain hydrogen bonding and \u03c0\u2013\u03c0 interactions, yielding a three-dimensional network.\n <\/jats:p>","DOI":"10.1107\/s2056989024009915","type":"journal-article","created":{"date-parts":[[2024,10,23]],"date-time":"2024-10-23T08:28:23Z","timestamp":1729672103000},"page":"1217-1220","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of\n catena<\/i>\n -poly[[diaquadiimidazolecobalt(II)]-\u03bc\n 2<\/sub>\n -2,3,5,6-tetrabromobenzene-1,4-dicarboxylato]"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7996-7836","authenticated-orcid":true,"given":"Hitoshi","family":"Kumagai","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7615-6517","authenticated-orcid":true,"given":"Satoshi","family":"Kawata","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00msqp585","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6305-6859","authenticated-orcid":true,"given":"Nobuhiro","family":"Ogihara","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,10,31]]},"reference":[{"key":"jp2013_bb1","doi-asserted-by":"crossref","first-page":"3268","DOI":"10.1002\/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U","volume":"38","author":"Cheetham","year":"1999","journal-title":"Angew. 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