{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,12,21]],"date-time":"2024-12-21T05:16:20Z","timestamp":1734758180972,"version":"3.32.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2024,10,24]],"date-time":"2024-10-24T00:00:00Z","timestamp":1729728000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,10,24]],"date-time":"2024-10-24T00:00:00Z","timestamp":1729728000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Vingroup Innovation Foundation","award":["VINIF.2023.ThS.066"],"award-info":[{"award-number":["VINIF.2023.ThS.066"]}]},{"name":"Hercules Foundation","award":["AKUL\/09\/0035"],"award-info":[{"award-number":["AKUL\/09\/0035"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,10,22]]},"published-print":{"date-parts":[[2024,11,1]]},"abstract":"<jats:p>Two new zinc(II) complexes, triethylammonium dichlorido[2-(4-nitrophenyl)-4-phenylquinolin-8-olato]zinc(II), (C<jats:sub>6<\/jats:sub>H<jats:sub>16<\/jats:sub>N){Zn(C<jats:sub>21<\/jats:sub>H<jats:sub>13<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)Cl<jats:sub>2<\/jats:sub>] (<jats:bold>ZnOQ<\/jats:bold>), and bis(triethylammonium) {2,2\u2032-[1,4-phenylenebis(nitrilomethylidyne)]diphenolato}bis[dichloridozinc(II)], (C<jats:sub>6<\/jats:sub>H<jats:sub>16<\/jats:sub>N)<jats:sub>2<\/jats:sub>[Zn<jats:sub>2<\/jats:sub>(C<jats:sub>20<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)Cl<jats:sub>4<\/jats:sub>] (<jats:bold>ZnBS<\/jats:bold>), were synthesized and their structures were determined using ESI\u2013MS spectrometry, <jats:sup>1<\/jats:sup>H NMR spectroscopy, and single-crystal X-ray diffraction. The results showed that the ligands 2-(4-nitrophenyl)-4-phenylquinolin-8-ol (<jats:bold>HOQ<\/jats:bold>) and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis(2-hydroxybenzylidene)benzene-1,4-diamine (<jats:bold>H<jats:sub>2<\/jats:sub>BS<\/jats:bold>) were deprotonated by triethyl-amine, forming the counter-ion Et<jats:sub>3<\/jats:sub>NH<jats:sup>+<\/jats:sup>, which interacts <jats:italic>via<\/jats:italic> an N\u2014H...O hydrogen bond with the ligand. The Zn<jats:sup>II<\/jats:sup> atoms have a distorted trigonal\u2013pyramidal (<jats:bold>ZnOQ<\/jats:bold>) and distorted tetrahedral (<jats:bold>ZnBS<\/jats:bold>) geometries with a coordination number of four, coordinating with the ligands <jats:italic>via<\/jats:italic> N and O atoms. The N atoms coordinating with Zn<jats:sup>II<\/jats:sup> correspond to the heterocyclic nitrogen for the <jats:bold>HOQ<\/jats:bold> ligand, while for the <jats:bold>H<jats:sub>2<\/jats:sub>BS<\/jats:bold> ligand, it is the nitrogen of the imine (CH=N). The crystal packing of <jats:bold>ZnOQ<\/jats:bold> is characterized by C\u2014H...\u03c0 interactions, while that of <jats:bold>ZnBS<\/jats:bold> by C\u2014H...Cl interactions. The emission spectra showed that <jats:bold>ZnBS<\/jats:bold> complex exhibits green fluorescence in the solid state with a small band-gap energy, and the <jats:bold>ZnOQ<\/jats:bold> complex does exhibit non-fluorescence.<\/jats:p>","DOI":"10.1107\/s2056989024010302","type":"journal-article","created":{"date-parts":[[2024,10,24]],"date-time":"2024-10-24T07:14:55Z","timestamp":1729754095000},"page":"1210-1216","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures and photophysical properties of mono- and dinuclear Zn<sup>II<\/sup> complexes flanked by triethylammonium"],"prefix":"10.1107","volume":"80","author":[{"given":"Hai","family":"Le Thi Hong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hien","family":"Nguyen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Duong","family":"Trinh Hong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ninh","family":"Nguyen Hoang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Khanh","family":"Nguyen Nhat","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2186-5209","authenticated-orcid":true,"given":"Luc","family":"Van Meervelt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,10,24]]},"reference":[{"key":"oo2008_bb1","doi-asserted-by":"crossref","first-page":"6033","DOI":"10.3390\/molecules27186033","volume":"27","author":"Chiyindiko","year":"2022","journal-title":"Molecules"},{"key":"oo2008_bb2","doi-asserted-by":"crossref","unstructured":"C\u00f4rte-Real, L., P\u00f3sa, V., Martins, M., Colucas, R., May, N. 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