{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:59:55Z","timestamp":1785427195451,"version":"3.56.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"crossref","award":["22BF037-03"],"award-info":[{"award-number":["22BF037-03"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"crossref","award":["22BF037-04"],"award-info":[{"award-number":["22BF037-04"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"crossref","award":["24BF037-03"],"award-info":[{"award-number":["24BF037-03"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"crossref"}]},{"name":"EURIZON","award":["871072"],"award-info":[{"award-number":["871072"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,10,23]]},"published-print":{"date-parts":[[2024,11,1]]},"abstract":"<jats:p>\n                    The unit cell of the title compound, [Ni(C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    ClN\n                    <jats:sub>6<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b72CH\n                    <jats:sub>3<\/jats:sub>\n                    OH, consists of a neutral complex and two methanol molecules. In the complex, the two tridentate 2-(3-(4-chlorophenyl)-1\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazol-5-yl)-6-(1\n                    <jats:italic>H<\/jats:italic>\n                    -pyrazol-1-yl)pyridine ligands coordinate to the central Ni\n                    <jats:sup>II<\/jats:sup>\n                    ion through the N atoms of the pyrazole, pyridine and triazole groups, forming a pseudooctahedral coordination sphere. Neighbouring tapered molecules are linked through weak C\u2014H(pz)...\u03c0(ph) interactions into monoperiodic chains, which are further linked through weak C\u2014H...N\/C interactions into diperiodic layers. The intermolecular contacts were quantified using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative contributions of the contacts to the crystal packing to be H...H 32.8%, C...H\/H...C 27.5%, N...H\/H...N 15.1%, and Cl...H\/H...Cl 14.0%. The average Ni\u2014N bond distance is 2.095\u2005\u00c5. Energy framework analysis at the HF\/3\u201321\u2005G theory level was performed to quantify the interaction energies in the crystal structure.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024010338","type":"journal-article","created":{"date-parts":[[2024,10,28]],"date-time":"2024-10-28T07:22:32Z","timestamp":1730100152000},"page":"1235-1239","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of bis{5-(4-chlorophenyl)-3-[6-(1\n                    <i>H<\/i>\n                    -pyrazol-1-yl)pyridin-2-yl]-1\n                    <i>H<\/i>\n                    -1,2,4-triazol-1-ido}nickel(II) methanol disolvate"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4818-8658","authenticated-orcid":true,"given":"Kateryna","family":"Znovjyak","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1222-4373","authenticated-orcid":true,"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0561n6946","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitriy M.","family":"Panov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8355-4938","authenticated-orcid":true,"given":"Nataliia S.","family":"Kariaka","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1092-8035","authenticated-orcid":true,"given":"Igor O.","family":"Fritsky","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey O.","family":"Malinkin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maksym","family":"Seredyuk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,10,31]]},"reference":[{"key":"tx2090_bb1","doi-asserted-by":"crossref","first-page":"11251","DOI":"10.1021\/jp301552u","volume":"116","author":"Bonhommeau","year":"2012","journal-title":"J. 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