{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T11:47:14Z","timestamp":1733399234121,"version":"3.30.1"},"reference-count":35,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T00:00:00Z","timestamp":1730764800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T00:00:00Z","timestamp":1730764800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,10,24]]},"published-print":{"date-parts":[[2024,12,1]]},"abstract":"<jats:p>Monoclinic single crystals of Cd<jats:sub>5<\/jats:sub>(TeO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> (space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>), pentacadmium tetrakis[oxidotellurate(IV)] dinitrate, and of Cd<jats:sub>4<\/jats:sub>Te<jats:sub>5<\/jats:sub>O<jats:sub>14<\/jats:sub> (space group <jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>), tetracadmium pentaoxidotellurate(IV), were obtained under the same hydrothermal conditions. Whereas the crystal structure of Cd<jats:sub>5<\/jats:sub>(TeO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> is distinctively layered, that of Cd<jats:sub>4<\/jats:sub>Te<jats:sub>5<\/jats:sub>O<jats:sub>14<\/jats:sub> exhibits a tri-periodic framework. In Cd<jats:sub>5<\/jats:sub>(TeO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>, the three Cd<jats:sup>II<\/jats:sup> atoms have coordination numbers (CN) of 7, 6 and 6. The two types of [CdO<jats:sub>6<\/jats:sub>] and the [CdO<jats:sub>7<\/jats:sub>] polyhedra [bond lengths range from 2.179\u2005(3) to 2.658\u2005(2)\u2005\u00c5] share corners and edges, resulting in layers extending parallel to (100). Both Te<jats:sup>IV<\/jats:sup> atoms are coordinated by three oxygen atoms in a trigonal\u2013pyramidal shape. The oxygen atoms of the isolated [TeO<jats:sub>3<\/jats:sub>] groups [bond lengths range from 1.847\u2005(3) to 1.886\u2005(3)\u2005\u00c5] all are part of the cadmium\u2013oxygen layer. The electron lone pairs \u03c8 of the Te<jats:sup>IV<\/jats:sup> atoms are directed away from the layer on both sides. The available interlayer space is co-occupied by the nitrate group, which is directly connected with two of its O atoms to the layer whereas the third O atom is solely bonded to the N atom and points towards the adjacent layer. In Cd<jats:sub>4<\/jats:sub>Te<jats:sub>5<\/jats:sub>O<jats:sub>14<\/jats:sub>, all three unique Cd<jats:sup>II<\/jats:sup> atoms are coordinated by six oxygen atoms, considering Cd\u2014O distances from 2.235\u2005(2) to 2.539\u2005(2)\u2005\u00c5. By edge- and corner-sharing, the distorted [CdO<jats:sub>6<\/jats:sub>] polyhedra form an open framework that is partially filled with three different stereochemically active Te<jats:sup>IV<\/jats:sup> atoms. All of them exhibit a CN of 4, with Te\u2014O bonds in a range from 1.859\u2005(2) to 2.476\u2005(2)\u2005\u00c5. The corresponding [TeO<jats:sub>4<\/jats:sub>] units are linked to each other by corner- and edge-sharing, forming infinite helical <jats:sup>1<\/jats:sup>\n                  <jats:sub>\u221e<\/jats:sub>[Te<jats:sub>10<\/jats:sub>O<jats:sub>28<\/jats:sub>] chains extending parallel to [203]. The connectivity in the chains can be described as (...\u2013\u22c4\u2013\u22c4=\u22c4\u2013\u22c4\u2013\u22c4\u2013\u22c4\u2013\u22c4=\u22c4\u2013\u22c4\u2013\u22c4\u2013...)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> where \u2018\u22c4\u2019 denotes a [TeO<jats:sub>4<\/jats:sub>] unit, \u2018\u2013\u2019 a linkage <jats:italic>via<\/jats:italic> corners and \u2018=\u2019 a linkage <jats:italic>via<\/jats:italic> edges. Such a structural motif is unprecedented in the crystal chemistry of oxidotellurate(IV) compounds.<\/jats:p>","DOI":"10.1107\/s2056989024010387","type":"journal-article","created":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T10:20:26Z","timestamp":1730802026000},"page":"1244-1249","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["The cadmium oxidotellurates(IV) Cd<sub>5<\/sub>(TeO<sub>3<\/sub>)<sub>4<\/sub>(NO<sub>3<\/sub>)<sub>2<\/sub> and Cd<sub>4<\/sub>Te<sub>5<\/sub>O<sub>14<\/sub>"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5336-4735","authenticated-orcid":true,"given":"Felix","family":"Eder","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5235-9910","authenticated-orcid":true,"given":"Matthias","family":"Weil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,11,5]]},"reference":[{"key":"pk2712_bb1","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1107\/S0108768190011041","volume":"47","author":"Brese","year":"1991","journal-title":"Acta Cryst. 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