{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T11:47:20Z","timestamp":1733399240136,"version":"3.30.1"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2024,11,8]],"date-time":"2024-11-08T00:00:00Z","timestamp":1731024000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,11,8]],"date-time":"2024-11-08T00:00:00Z","timestamp":1731024000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"The Asia Research Center at Vietnam National University, Hanoi","award":["CA.22.06A"],"award-info":[{"award-number":["CA.22.06A"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,11,4]]},"published-print":{"date-parts":[[2024,12,1]]},"abstract":"<jats:p>Reaction between equimolar amounts of 3,3,3\u2032,3\u2032-tetraethyl-1,1\u2032-(furan-2,5-dicarbonyl)bis(thiourea) (<jats:bold>H<jats:sub>2<\/jats:sub>L<\/jats:bold>) and CuCl<jats:sub>2<\/jats:sub>\u00b72H<jats:sub>2<\/jats:sub>O in methanol in the presence of the supporting base Et<jats:sub>3<\/jats:sub>N gave rise to a neutral dinuclear complex bis[\u03bc-3,3,3\u2032,3\u2032-tetraethyl-1,1\u2032-(furan-2,5-dicarbonyl)bis(thioureato)]dicopper(II) dichloromethane disolvate, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>16<\/jats:sub>H<jats:sub>22<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>3<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> or [Cu<jats:sub>2<\/jats:sub>(<jats:italic>L<\/jats:italic>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>. The aroylbis(thioureas) are doubly deprotonated and the resulting anions {<jats:italic>L<\/jats:italic>\n                  <jats:sup>2\u2013<\/jats:sup>} bond to metal ions through (<jats:italic>S<\/jats:italic>,<jats:italic>O<\/jats:italic>)-chelating moieties. The copper atoms adopt a virtually <jats:italic>cis<\/jats:italic>-square-planar environment. In the crystal, adjacent [Cu<jats:sub>2<\/jats:sub>(<jats:italic>L<\/jats:italic>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> units are linked into polymeric chains along the <jats:italic>a-<\/jats:italic>axis direction by intermolecular coordinative Cu...S interactions. The co-crystallized solvent molecules play a vital role in the crystal packing. In particular, weak C\u2014H<jats:sub>furan<\/jats:sub>...Cl and C\u2014H<jats:sub>ethyl<\/jats:sub>...Cl contacts consolidate the three-dimensional supramolecular architecture.<\/jats:p>","DOI":"10.1107\/s2056989024010703","type":"journal-article","created":{"date-parts":[[2024,11,8]],"date-time":"2024-11-08T08:28:53Z","timestamp":1731054533000},"page":"1266-1269","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a solvated dinuclear Cu<sup>II<\/sup> complex derived from 3,3,3\u2032,3\u2032-tetraethyl-1,1\u2032-(furan-2,5-dicarbonyl)bis(thiourea)"],"prefix":"10.1107","volume":"80","author":[{"given":"Canh Dinh","family":"Le","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hoang Phuc","family":"Nguyen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0619-2720","authenticated-orcid":true,"given":"Chien Thang","family":"Pham","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,11,8]]},"reference":[{"key":"oo2007_bb1","doi-asserted-by":"crossref","first-page":"119019","DOI":"10.1016\/j.ica.2019.119019","volume":"495","author":"Barnard","year":"2019","journal-title":"Inorg. 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