{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:32:00Z","timestamp":1785403920527,"version":"3.56.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2024,11,28]],"date-time":"2024-11-28T00:00:00Z","timestamp":1732752000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,11,28]],"date-time":"2024-11-28T00:00:00Z","timestamp":1732752000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,11,19]]},"published-print":{"date-parts":[[2024,12,1]]},"abstract":"<jats:p>\n                    1-(1-Chloroethyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline was synthesized through the reaction of homoveratrylamine with racemic lactic acid. The formation of two enantiomers,\n                    <jats:italic>RR<\/jats:italic>\n                    and\n                    <jats:italic>SS<\/jats:italic>\n                    , was detected by performing X-ray diffraction analysis on their chloride salts. The asymmetric unit of the crystal consists of a C\n                    <jats:sub>13<\/jats:sub>\n                    H\n                    <jats:sub>19<\/jats:sub>\n                    ClNO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    molecular cation and a Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    anion. Two protonated enantiomers of the title compound, with\n                    <jats:italic>RR<\/jats:italic>\n                    and\n                    <jats:italic>SS<\/jats:italic>\n                    configurations of the chiral atoms, are connected into hydrogen-bonded dimers bridged by Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    anions. Weak C\u2014H...Cl interactions lead to the formation of a chain running along the\n                    <jats:italic>a-<\/jats:italic>\n                    axis direction of the unit cell, which corresponds to the longest dimension (the preferential growth direction) of the needle-shaped monocrystal. The crystal studied was refined as a two-component twin.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024011277","type":"journal-article","created":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T01:56:48Z","timestamp":1732240608000},"page":"1322-1325","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of 1-(1-chloroethyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinolinium chloride"],"prefix":"10.1107","volume":"80","author":[{"given":"Ziroat E.","family":"Urunbaeva","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02b6gy972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5741-6347","authenticated-orcid":true,"given":"Kambarali K.","family":"Turgunov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdusalom Sh.","family":"Saidov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02b6gy972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valentina I.","family":"Vinogradova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,11,28]]},"reference":[{"key":"ny2008_bb1","doi-asserted-by":"crossref","first-page":"650","DOI":"10.3390\/90800650","volume":"9","author":"El Antri","year":"2004","journal-title":"Molecules"},{"key":"ny2008_bb2","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1021\/jm0210008","volume":"46","author":"Gitto","year":"2003","journal-title":"J. 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