{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:31:47Z","timestamp":1785407507968,"version":"3.56.0"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T00:00:00Z","timestamp":1735689600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T00:00:00Z","timestamp":1735689600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002241","name":"Japan Science and Technology Agency","doi-asserted-by":"crossref","award":["JPMJCR2001"],"award-info":[{"award-number":["JPMJCR2001"]}],"id":[{"id":"10.13039\/501100002241","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Network Joint Research Center for Materials and Devices","award":["24DS0570"],"award-info":[{"award-number":["24DS0570"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,12,4]]},"published-print":{"date-parts":[[2025,1,1]]},"abstract":"<jats:p>\n                    The asymmetric unit of the title compound is composed of one host molecule,\n                    <jats:italic>anti<\/jats:italic>\n                    -4-(1\n                    <jats:sup>9<\/jats:sup>\n                    <jats:italic>H<\/jats:italic>\n                    ,5\n                    <jats:sup>9<\/jats:sup>\n                    <jats:italic>H<\/jats:italic>\n                    -3-aza-1,5(3,9)-dicarbazolacyclooctaphane-3-yl)benzonitrile and one dichloromethane solvate molecule, C\n                    <jats:sub>36<\/jats:sub>\n                    H\n                    <jats:sub>28<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    \u00b7CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    . The host molecule possesses a planar chirality but crystallizes as a racemate in the space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    . It adopts an\n                    <jats:italic>anti<\/jats:italic>\n                    -configuration, in which two carbazole rings are partially overlapped with a parallel orientation. The two carbazole ring systems are slightly bent, and the C atoms at the 3- and 1-positions show the largest deviations from the mean planes. The dihedral angle between two carbazole rings is 9.42\u2005(3)\u00b0, forming an intramolecular parallel \u03c0\u2013\u03c0 interaction [\n                    <jats:italic>Cg<\/jats:italic>\n                    ...\n                    <jats:italic>Cg<\/jats:italic>\n                    = 3.2755\u2005(9)\u2005\u00c5]. In the crystal, the molecules are linked\n                    <jats:italic>via<\/jats:italic>\n                    host\u2013host and host\u2013guest C\u2014H...\u03c0 interactions, forming chain structures along the\n                    <jats:italic>a<\/jats:italic>\n                    -axis direction. The molecules are linked into a ribbon structure along the\n                    <jats:italic>c-<\/jats:italic>\n                    axis direction by further C\u2014H...\u03c0 interactions. As a result, The molecules are cross-linked by C\u2014H...\u03c0 interactions into a three-dimensional network.\n                  <\/jats:p>","DOI":"10.1107\/s2056989024011782","type":"journal-article","created":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T02:01:37Z","timestamp":1733364097000},"page":"20-23","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of\n                    <i>anti<\/i>\n                    -10-(4-cyanophenyl)-10,11,22,23-tetrahydro-9\n                    <i>H<\/i>\n                    ,21\n                    <i>H<\/i>\n                    -5,8:15,12-bis(metheno)[1,5,11]triazacyclohexadecino[1,16-\n                    <i>a<\/i>\n                    :5,6-\n                    <i>a<\/i>\n                    \u2032]diindole dichloromethane monosolvate"],"prefix":"10.1107","volume":"81","author":[{"given":"Koji","family":"Kubono","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keita","family":"Tani","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4122-3345","authenticated-orcid":true,"given":"Yukiyasu","family":"Kashiwagi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,1,1]]},"reference":[{"key":"ox2009_bb1","doi-asserted-by":"crossref","first-page":"19681","DOI":"10.1021\/jp051539s","volume":"109","author":"Benten","year":"2005","journal-title":"J. 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Rigaku Oxford Diffraction Ltd, Yarnton, England."},{"key":"ox2009_bb10","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/0032-3861(96)81597-7","volume":"37","author":"Sakai","year":"1996","journal-title":"Polymer"},{"key":"ox2009_bb11","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ox2009_bb12","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ox2009_bb13","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S2056989019016244","volume":"76","author":"Spek","year":"2020","journal-title":"Acta Cryst. E"},{"key":"ox2009_bb14","doi-asserted-by":"crossref","first-page":"2057","DOI":"10.1021\/acs.jpca.0c00286","volume":"124","author":"Tani","year":"2020","journal-title":"J. Phys. Chem. 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