{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T01:10:28Z","timestamp":1780103428391,"version":"3.54.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T00:00:00Z","timestamp":1735689600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T00:00:00Z","timestamp":1735689600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,12,4]]},"published-print":{"date-parts":[[2025,1,1]]},"abstract":"<jats:p>The title compound, [CdBr<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, was prepared by the reaction of cadmium bromide with 2,5-dimethylpyrazine in water. Its asymmetric unit consists of one Cd cation and one 2,5-dimethylpyrazine ligand that are located on a crystallographic mirror plane as well as one bromide anion that occupies a general position. The Cd cations are sixfold coordinated by four bromide anions and two 2,5-dimethylpyrazine ligands within slightly distorted <jats:italic>trans<\/jats:italic>-CdBr<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub> octahedra. The cations are linked into [100] chains <jats:italic>via<\/jats:italic> pairs of bridging bromide anions that are further connected into (001) layers by the bridging 2,5-dimethylpyrazine ligands. Powder X-ray diffraction (PXRD) shows that a pure crystalline phase has been obtained. Thermogravimetry coupled to differential thermoanalysis (TG-TDA) reveal that the 2,5-dimethylpyrazine ligands are removed in two separate steps leading to the formation of a compound with the composition (CdBr<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(2,5-dimethylpyrazine) that decomposes into CdBr<jats:sub>2<\/jats:sub> upon further heating. PXRD measurements of the residue obtained after the first mass loss show that a new crystalline phase has been formed.<\/jats:p>","DOI":"10.1107\/s2056989024011824","type":"journal-article","created":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T08:26:57Z","timestamp":1734078417000},"page":"29-33","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis, crystal structure and thermal properties of poly[di-\u03bc-bromido-(\u03bc-2,5-dimethylpyrazine)cadmium(II)]"],"prefix":"10.1107","volume":"81","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,1,1]]},"reference":[{"key":"hb8115_bb1","doi-asserted-by":"crossref","first-page":"2153","DOI":"10.1016\/j.poly.2005.03.036","volume":"24","author":"Awwadi","year":"2005","journal-title":"Polyhedron"},{"key":"hb8115_bb2","doi-asserted-by":"crossref","first-page":"1303","DOI":"10.1021\/ic50019a023","volume":"3","author":"Ayres","year":"1964","journal-title":"Inorg. 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