{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,7]],"date-time":"2025-02-07T05:08:56Z","timestamp":1738904936833,"version":"3.37.0"},"reference-count":30,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2025,1,3]],"date-time":"2025-01-03T00:00:00Z","timestamp":1735862400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,1,3]],"date-time":"2025-01-03T00:00:00Z","timestamp":1735862400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2024,12,20]]},"published-print":{"date-parts":[[2025,2,1]]},"abstract":"<jats:p>The asymmetric units of <jats:italic>catena<\/jats:italic>-poly[[(1,4,8,11-tetraazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>11<\/jats:sup>)nickel(II)]-\u03bc<jats:sub>2<\/jats:sub>-sulfato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>], [Ni(SO<jats:sub>4<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>I<\/jats:bold>), and <jats:italic>catena<\/jats:italic>-poly[[(1,4,8,11-tetraazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>11<\/jats:sup>)nickel(II)]-\u03bc<jats:sub>2<\/jats:sub>-sulfato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>] hemi[4,4\u2032,4\u2032\u2032,4\u2032\u2032\u2032-(2,2\u2032,4,4\u2032,6,6\u2032-hexamethyl-[1,1\u2032-biphenyl]-3,3\u2032,5,5\u2032-tetrayl)tetrabenzoic acid] nonahydrate], {[Ni(SO<jats:sub>4<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub>2<\/jats:sub>\u00b7C<jats:sub>46<\/jats:sub>H<jats:sub>38<\/jats:sub>O<jats:sub>8<\/jats:sub>\u00b718H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>II<\/jats:bold>), consist of two crystallographically unique centrosymmetric macrocyclic dications and a sulfate dianion. In <jats:bold>II<\/jats:bold> it includes additionally a molecule of the undissociated acid (2,2\u2032,4,4\u2032,6,6\u2032-hexamethyl[1,1\u2032-biphenyl]-3,3\u2032,5,5\u2032-tetrayl)tetra(benzoic acid) located on a crystallographic twofold axis and nine highly disordered water molecules of crystallization. In both compounds, the metal ions are coordinated in the equatorial plane by the four secondary N atoms of the macrocyclic ligand, which adopts the most energetically stable <jats:italic>trans<\/jats:italic>-III conformation. Two O atoms of the sulfate anions occupy the <jats:italic>trans<\/jats:italic>-axial positions resulting in a slightly tetragonally distorted <jats:italic>trans<\/jats:italic>-NiN<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub> octahedral coordination geometry. The crystals of both compounds are composed of parallel coordination polymeric chains running along the [101] and [100] directions in <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold>, respectively. The distances between the neighboring metal ions in the chains are significantly different [6.5121\u2005(6)\u2005\u00c5 in <jats:bold>I<\/jats:bold> and 6.0649\u2005(3)\u2005\u00c5 in <jats:bold>II<\/jats:bold>] and this peculiarity is explained by the different spatial directivity of the Ni\u2014O coordination bonds (different S\u2014O\u2014Ni angles). As a result of the C\u2014H...O hydrogen bonds between the methylene groups of the macrocyclic ligands and the non-coordinated O atoms of the sulfate anion, the coordination-polymeric chains in <jats:bold>I<\/jats:bold> are arranged in the two-dimensional layers oriented parallel to the (010) and (10<jats:overline>1<\/jats:overline>) planes, the intersection of which provides the three-dimensional coherence of the crystals. The three-dimensional supramolecular structure of the crystals <jats:bold>II<\/jats:bold> is determined by the network of strong hydrogen bonds formed by the carboxylic acid and the non-coordinated O atoms of the sulfate anions.<\/jats:p>","DOI":"10.1107\/s2056989024012337","type":"journal-article","created":{"date-parts":[[2025,1,3]],"date-time":"2025-01-03T08:52:19Z","timestamp":1735894339000},"page":"90-95","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Syntheses and structures of two coordination polymers formed by Ni(cyclam)<sup>2+<\/sup> cations and sulfate anions"],"prefix":"10.1107","volume":"81","author":[{"given":"Liudmyla V.","family":"Tsymbal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina L.","family":"Andriichuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lucian G.","family":"Bahrin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,1,3]]},"reference":[{"key":"hb8118_bb1","doi-asserted-by":"crossref","first-page":"114128","DOI":"10.1016\/j.poly.2019.114128","volume":"173","author":"Bahrin","year":"2019","journal-title":"Polyhedron"},{"key":"hb8118_bb2","doi-asserted-by":"crossref","first-page":"4197","DOI":"10.1021\/ic00243a028","volume":"25","author":"Barefield","year":"1986","journal-title":"Inorg. 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