{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T18:22:52Z","timestamp":1790792572969,"version":"4.1.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"National Science Foundation Major Research Instrumentation fund","award":["2215812"],"award-info":[{"award-number":["2215812"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,1,6]]},"published-print":{"date-parts":[[2025,2,1]]},"abstract":"<jats:p>\n                    The reactions of triphenylsulfonium chloride ([TPS][Cl]) with various acids in methanol yield the corresponding salts triphenylsulfonium triiodide, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    \u00b7I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    or [TPS][I\n                    <jats:sub>3<\/jats:sub>\n                    ] (\n                    <jats:bold>I<\/jats:bold>\n                    ), triphenylsulfonium perchlorate, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    \u00b7ClO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    or [TPS][ClO\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>II<\/jats:bold>\n                    ), and triphenylsulfonium hexafluorophosphate, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S\n                    <jats:sup>+<\/jats:sup>\n                    \u00b7PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    or [TPS][PF\n                    <jats:sub>6<\/jats:sub>\n                    ] (\n                    <jats:bold>III<\/jats:bold>\n                    ), as crystalline products. These crystals were structurally characterized by single-crystal X-ray diffraction. In all three compounds, the sulfur atom in the triphenylsulfonium cation adopts a distorted trigonal\u2013pyramidal geometry. [TPS][I\n                    <jats:sub>3<\/jats:sub>\n                    ] (\n                    <jats:bold>I<\/jats:bold>\n                    ) and [TPS][PF\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:bold>(III<\/jats:bold>\n                    ) both crystallize in the space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    , while [TPS][ClO\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>II<\/jats:bold>\n                    ) crystallizes in\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    . The S\u2014C bond lengths are comparable across the three salts, and the S\u2014C\u2014S bond angles are consistently between 102 and 106\u00b0. Hirshfeld surface analyses reveal that each structure is dominated by hydrogen-based intermolecular contacts, supplemented by anion-specific interactions such as I...H in (\n                    <jats:bold>I<\/jats:bold>\n                    ), O...H in (\n                    <jats:bold>II<\/jats:bold>\n                    ), and F...H in (\n                    <jats:bold>III<\/jats:bold>\n                    ). These contacts organize the ions into mono-periodic ribbon- or chain-like arrangements. No significant \u03c0\u2013\u03c0 stacking is observed.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025000118","type":"journal-article","created":{"date-parts":[[2025,1,8]],"date-time":"2025-01-08T02:08:11Z","timestamp":1736302091000},"page":"114-119","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Crystal structures of three salts of the triphenylsulfonium ion"],"prefix":"10.1107","volume":"81","author":[{"given":"Rylan","family":"Artis","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Waylan","family":"Callaway","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-0752-7550","authenticated-orcid":true,"given":"Elizabeth","family":"Heyward","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naomi","family":"Reyes","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gavin","family":"Roberts","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaitlyn","family":"Van Ostenbridge","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8373-1495","authenticated-orcid":true,"given":"Clifford W.","family":"Padgett","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3494-8652","authenticated-orcid":true,"given":"Will E.","family":"Lynch","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,1,10]]},"reference":[{"key":"ej2011_bb1","doi-asserted-by":"crossref","first-page":"315","DOI":"10.1042\/bj1560315","volume":"156","author":"Barrett","year":"1976","journal-title":"Biochem. 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