{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T04:05:37Z","timestamp":1743480337942,"version":"3.40.3"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2025,2,14]],"date-time":"2025-02-14T00:00:00Z","timestamp":1739491200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,2,14]],"date-time":"2025-02-14T00:00:00Z","timestamp":1739491200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,2,6]]},"published-print":{"date-parts":[[2025,3,1]]},"abstract":"<jats:p>The present study reports on the molecular structures and syntheses of 1,1\u2032,1\u2032\u2032-[(2-bromoethoxy)methanetriyl]tribenzene, C<jats:sub>21<\/jats:sub>H<jats:sub>19<\/jats:sub>BrO, and 1,1\u2032,1\u2032\u2032-[(2-iodoethoxy)methanetriyl]tribenzene, C<jats:sub>21<\/jats:sub>H<jats:sub>19<\/jats:sub>IO. Both compounds crystallized from a saturated solution in THF by slow vapour diffusion of <jats:italic>n<\/jats:italic>-hexane in the monoclinic space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>. While the two independent molecules in the asymmetric unit of 1,1\u2032,1\u2032\u2032-[(2-iodoethoxy)methanetriyl]tribenzene show no close contacts to other molecules, in the structure of 1,1\u2032,1\u2032\u2032-[(2-bromoethoxy)methanetriyl]tribenzene the molecules interact with each other <jats:italic>via<\/jats:italic> C\u2014H...\u03c0 contacts.<\/jats:p>","DOI":"10.1107\/s2056989025001124","type":"journal-article","created":{"date-parts":[[2025,2,14]],"date-time":"2025-02-14T08:49:20Z","timestamp":1739522960000},"page":"214-218","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and structure of 1,1\u2032,1\u2032\u2032-[(2-bromoethoxy)methanetriyl]tribenzene and 1,1\u2032,1\u2032\u2032-[(2-iodoethoxy)methanetriyl]tribenzene"],"prefix":"10.1107","volume":"81","author":[{"given":"Julian","family":"Fischer","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9339-5165","authenticated-orcid":true,"given":"Marian","family":"Hebenbrock","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,2,14]]},"reference":[{"key":"yy2014_bb1","unstructured":"Bruker (2021). 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