{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T18:07:39Z","timestamp":1785434859121,"version":"3.56.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T00:00:00Z","timestamp":1747094400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T00:00:00Z","timestamp":1747094400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["CHE1606556"],"award-info":[{"award-number":["CHE1606556"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,5,5]]},"published-print":{"date-parts":[[2025,6,1]]},"abstract":"<jats:p>\n                    The structures of four palladium complexes serendipitously isolated after palladium-catalyzed Sonogashira coupling of aryl iodides with terminal alkynes are reported, namely [3,5-bis(trifluoromethyl)phenyl]iodidobis(triphenylphosphane)palladium(II), [Pd(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    F\n                    <jats:sub>6<\/jats:sub>\n                    )I(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ],\n                    <jats:bold>1<\/jats:bold>\n                    , (3,5-dinitrophenyl)iodidobis(triphenylphosphane)palladium(II) ethyl acetate monosolvate, [Pd(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )I(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7C\n                    <jats:sub>4<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ,\n                    <jats:bold>2<\/jats:bold>\n                    , (2,3,4-difluorophenyl)iodidobis(triphenylphosphane)palladium(II), [Pd(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>3<\/jats:sub>\n                    )I(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ],\n                    <jats:bold>3<\/jats:bold>\n                    , and (2,4,6-difluorophenyl)iodidobis(triphenylphosphane)palladium(II) dichloromethane disolvate, [Pd(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>3<\/jats:sub>\n                    )I(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b72CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    ,\n                    <jats:bold>4<\/jats:bold>\n                    . These complexes were isolated as red\/orange crystals that co-eluted with the organic products of each reaction during flash chromatography. These complexes are oxidative addition products ArPdI(PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    where Ar = 3,5-bis(trifluoromethyl)phenyl, 3,5-dinitrophenyl, 2,3,4-trifluorophenyl and 2,4,6-trifluoro-3,5-diiodophenyl. The isolation of these complexes provides some insight into the possible fate of the palladium catalyst.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025004025","type":"journal-article","created":{"date-parts":[[2025,5,9]],"date-time":"2025-05-09T01:53:57Z","timestamp":1746755637000},"page":"492-496","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Phenyl palladium(II) iodide complexes isolated after Sonogashira coupling of iodobenzenes with terminal alkynes"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6465-1879","authenticated-orcid":true,"given":"Eric","family":"Bosch","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01d2sez20","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,5,13]]},"reference":[{"key":"jy2058_bb1","doi-asserted-by":"crossref","first-page":"1141","DOI":"10.1107\/S1600576720007438","volume":"53","author":"Barbour","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"jy2058_bb2","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jy2058_bb3","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1107\/S0108768102003324","volume":"58","author":"Bruno","year":"2002","journal-title":"Acta Cryst. B"},{"key":"jy2058_bb4","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"jy2058_bb5","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"jy2058_bb6","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"jy2058_bb7","doi-asserted-by":"crossref","first-page":"4043","DOI":"10.1021\/cg100737c","volume":"10","author":"Momose","year":"2010","journal-title":"Cryst. Growth Des."},{"key":"jy2058_bb8","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jy2058_bb9","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/S0022-328X(02)01158-0","volume":"653","author":"Sonogashira","year":"2002","journal-title":"J. Organomet. Chem."},{"key":"jy2058_bb10","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."},{"key":"jy2058_bb11","doi-asserted-by":"crossref","first-page":"4711","DOI":"10.1021\/om049580p","volume":"23","author":"Vicente","year":"2004","journal-title":"Organometallics"},{"key":"jy2058_bb12","doi-asserted-by":"crossref","first-page":"3834","DOI":"10.1021\/acs.orglett.1c00910","volume":"23","author":"Xu","year":"2021","journal-title":"Org. Lett."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/06\/00\/jy2058\/jy2058.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/06\/00\/jy2058\/jy2058.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,6,6]],"date-time":"2025-06-06T03:53:35Z","timestamp":1749182015000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989025004025"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,13]]},"references-count":12,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2025,6]]}},"alternative-id":["S2056989025004025"],"URL":"https:\/\/doi.org\/10.1107\/s2056989025004025","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy2058sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20581sup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20581sup6.cdx","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20582sup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20582sup7.cdx","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20583sup4.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20583sup8.cdx","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20584sup5.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025004025\/jy20584sup9.cdx","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,13]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?jy2058","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"3 March 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"5 May 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 May 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?jy2058"}},{"value":"\u00a9 2025 Eric Bosch","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}