{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:16:14Z","timestamp":1785420974124,"version":"3.56.0"},"reference-count":37,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T00:00:00Z","timestamp":1747094400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T00:00:00Z","timestamp":1747094400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,5,6]]},"published-print":{"date-parts":[[2025,6,1]]},"abstract":"<jats:p>\n                    Structural characteristics are reported for two thioether\u2013ketones,\n                    <jats:italic>\n                      <jats:bold>Dtdpe<\/jats:bold>\n                    <\/jats:italic>\n                    and\n                    <jats:italic>\n                      <jats:bold>Mtdp<\/jats:bold>\n                    <\/jats:italic>\n                    [2-({2-[(2-oxo-2-phenylethyl)sulfanyl]ethyl}sulfanyl)-1-phenylethan-1-one, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    , and 2-[(2-oxo-2-phenylethyl)sulfanyl]-1-phenylethan-1-one, C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>14<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S], and for related derivatives, the bis(pyridylhydrazones)\n                    <jats:italic>\n                      <jats:bold>Dhpk<\/jats:bold>\n                    <\/jats:italic>\n                    and\n                    <jats:italic>\n                      <jats:bold>Prpsb<\/jats:bold>\n                    <\/jats:italic>\n                    [2-((2\n                    <jats:italic>E<\/jats:italic>\n                    )-2-{(2\n                    <jats:italic>Z<\/jats:italic>\n                    )-2-phenyl-2-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethylidene}hydrazin-1-yl)pyridine, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>16<\/jats:sub>\n                    N\n                    <jats:sub>6<\/jats:sub>\n                    , and 2-[(2\n                    <jats:italic>Z<\/jats:italic>\n                    ,12\n                    <jats:italic>Z<\/jats:italic>\n                    )-3,12-diphenyl-14-(pyridin-2-yl)-5,10-dithia-1,2,13,14-tetraazatetradeca-2,12-dien-1-yl]pyridine, C\n                    <jats:sub>30<\/jats:sub>\n                    H\n                    <jats:sub>32<\/jats:sub>\n                    N\n                    <jats:sub>6<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    ], as well as for the macrocyclic thiocarbohydrazide derivative\n                    <jats:italic>\n                      <jats:bold>Ctrsp<\/jats:bold>\n                    <\/jats:italic>\n                    [(3\n                    <jats:italic>E<\/jats:italic>\n                    ,8\n                    <jats:italic>Z<\/jats:italic>\n                    )-3,9-dimethyl-1,11-dithia-4,5,7,8-tetraazacyclotetradeca-3,8-diene-6-thione, C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    ]. Three of the five compounds exhibit conformational enantiomerism in the solid state. The occurrence of intra- and intermolecular hydrogen bonding is commented upon through quantum mechanical (DFT) calculations. Weak C\u2014H...S interactions are noted, while stronger N\u2014H...N and N\u2014H...S hydrogen bridges are delineated.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025004037","type":"journal-article","created":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T03:21:49Z","timestamp":1747106509000},"page":"520-529","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Some thioether-ketones and their related derivatives"],"prefix":"10.1107","volume":"81","author":[{"given":"Molly A.","family":"O'Connor","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04bdffz58","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6625-6744","authenticated-orcid":true,"given":"Anna V.","family":"Pavlishchuk","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02we6hx96","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2770-7076","authenticated-orcid":true,"given":"Raymond J.","family":"Butcher","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05gt1vc06","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vitaly V.","family":"Pavlishchuk","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02we6hx96","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0706-7377","authenticated-orcid":true,"given":"Anthony W.","family":"Addison","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04bdffz58","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,5,13]]},"reference":[{"key":"jy2055_bb1","unstructured":"Apple, Inc. 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