{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:12:20Z","timestamp":1785420740222,"version":"3.56.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2025,6,24]],"date-time":"2025-06-24T00:00:00Z","timestamp":1750723200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,6,24]],"date-time":"2025-06-24T00:00:00Z","timestamp":1750723200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,6,18]]},"published-print":{"date-parts":[[2025,7,1]]},"abstract":"<jats:p>\n                    The coordination complex [Zn(C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    NS\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )] or [Zn(MBT)\n                    <jats:sub>2<\/jats:sub>\n                    (phen)], was synthesized using ethanol solutions of Zn(CH\n                    <jats:sub>3<\/jats:sub>\n                    COO)\n                    <jats:sub>2<\/jats:sub>\n                    \u00b72H\n                    <jats:sub>2<\/jats:sub>\n                    O, 1,10-phenanthroline (phen) and 2-mercaptobenzothiazole (MBTH-neutral). Single-crystal X-ray diffraction analysis revealed that the zinc atom resides on a crystallographic twofold axis within the asymmetric unit. In the complex, the zinc atom coordinates two 2-mercaptobenzothiazolate (MBT; anionic form of MBTH) ligands in a monodentate fashion through their sulfur atoms, while phenanthroline acts as a bidentate ligand, chelating the zinc center. Further structural analysis, including Hirshfeld surface and two-dimensional fingerprint plot studies, indicated the presence of multiple intermolecular interactions, particularly C\u2014H...N and C\u2014H...\u03c0 interactions, contributing to the cohesion and packing of the crystal structure.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025005468","type":"journal-article","created":{"date-parts":[[2025,6,23]],"date-time":"2025-06-23T02:03:49Z","timestamp":1750644229000},"page":"642-645","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and crystal structure analysis of bis(benzothiazole-2-thiolato-\u03ba\n                    <i>S<\/i>\n                    )(1,10-phenanthroline-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032)zinc(II)"],"prefix":"10.1107","volume":"81","author":[{"given":"Gulchekhra","family":"Abdullayeva","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9218-5596","authenticated-orcid":true,"given":"Batirbay","family":"Torambetov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shakhnoza","family":"Kadirova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2606-3221","authenticated-orcid":true,"given":"Shahlo","family":"Daminova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,6,24]]},"reference":[{"key":"ox2015_bb1","doi-asserted-by":"crossref","first-page":"743","DOI":"10.1039\/C39760000743","author":"Ashworth","year":"1976","journal-title":"J. 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Cryst."},{"key":"ox2015_bb11","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"ox2015_bb12","doi-asserted-by":"crossref","first-page":"3528","DOI":"10.1021\/ic50202a047","volume":"18","author":"Jeannin","year":"1979","journal-title":"Inorg. Chem."},{"key":"ox2015_bb13","first-page":"233","volume":"222","author":"Jin","year":"2007","journal-title":"Z. Krist. New Cryst. Struct."},{"key":"ox2015_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"ox2015_bb15","doi-asserted-by":"crossref","first-page":"1379","DOI":"10.1021\/ic302063u","volume":"52","author":"Li","year":"2013","journal-title":"Inorg. Chem."},{"key":"ox2015_bb16","unstructured":"Nishio, M., Hirota, M. & Umezawa, Y. (1998). The C\u2014H...\u03c0 interaction: evidence, nature, and consequences. New York: John Wiley & Sons."},{"key":"ox2015_bb17","doi-asserted-by":"crossref","first-page":"510","DOI":"10.1107\/S0909049508015173","volume":"15","author":"Pattanasiriwisawa","year":"2008","journal-title":"J. Synchrotron Rad."},{"key":"ox2015_bb18","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1107\/S2056989022000792","volume":"78","author":"Rakhmonova","year":"2022","journal-title":"Acta Cryst. E"},{"key":"ox2015_bb19","doi-asserted-by":"crossref","first-page":"2283","DOI":"10.1039\/D2CC06596G","volume":"59","author":"Seo","year":"2023","journal-title":"Chem. Commun."},{"key":"ox2015_bb20","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. 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