{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T08:12:22Z","timestamp":1761293542639,"version":"build-2065373602"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T00:00:00Z","timestamp":1751328000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T00:00:00Z","timestamp":1751328000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100012541","name":"Herculesstichting","doi-asserted-by":"publisher","award":["AKUL\/09\/0035"],"award-info":[{"award-number":["AKUL\/09\/0035"]}],"id":[{"id":"10.13039\/501100012541","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,6,25]]},"published-print":{"date-parts":[[2025,8,1]]},"abstract":"<jats:p>\n                    The title complex, [Pt(C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    )Cl(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>33<\/jats:sub>\n                    P)], was synthesized by the reaction of [PtCl(C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    )(\u03b7\n                    <jats:sup>2<\/jats:sup>\n                    -C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    )] and PCy\n                    <jats:sub>3<\/jats:sub>\n                    at room temperature for 2\u2005h with a yield of 80%. The deprotonated 5-nitroquinoline-8-ol (C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) anion coordinates to the metal atom in a bidentate mode\n                    <jats:italic>via<\/jats:italic>\n                    its N and O atoms with a N\u2014Pt\u2014O bite angle of 80.0\u2005(3)\u00b0. The tricyclohexylphosphine P atom is in a\n                    <jats:italic>trans<\/jats:italic>\n                    position with respect to the N atom in the square-planar coordination environment of the metal atom. The packing features zigzag chains linked by C\u2014H...O interactions and continuous channels occupied by disordered solvent molecules, both running in the\n                    <jats:italic>a<\/jats:italic>\n                    -axis direction. The complex shows weak activity against four cancer cell lines with IC\n                    <jats:sub>50<\/jats:sub>\n                    values &gt; 120\u2005\u00b5\n                    <jats:italic>M<\/jats:italic>\n                    , but significant catalytic ability and selectivity for hydrosilylation between phenylacetylene and triethylsilane.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025005766","type":"journal-article","created":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T02:25:52Z","timestamp":1750904752000},"page":"657-661","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, structure, catalytic and cytotoxic activities of chlorido(5-nitroquinolin-8-olato-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>O<\/i>\n                    )(tricyclohexylphosphine-\u03ba\n                    <i>P<\/i>\n                    )platinum(II)"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0843-7237","authenticated-orcid":true,"given":"Nguyen Thi Thanh","family":"Chi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nguyen Tran Huong","family":"Ly","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Doan Duc","family":"Hieu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2186-5209","authenticated-orcid":true,"given":"Luc","family":"Van Meervelt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,7,1]]},"reference":[{"key":"hb8142_bb1","doi-asserted-by":"crossref","first-page":"121435","DOI":"10.1016\/j.jorganchem.2020.121435","volume":"923","author":"Afanasenko","year":"2020","journal-title":"J. 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