{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T23:01:49Z","timestamp":1788822109940,"version":"build-2803163510"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2025,7,4]],"date-time":"2025-07-04T00:00:00Z","timestamp":1751587200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,7,4]],"date-time":"2025-07-04T00:00:00Z","timestamp":1751587200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,6,25]]},"published-print":{"date-parts":[[2025,8,1]]},"abstract":"<jats:p>\n                    In the title solvated molecular salt, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>22<\/jats:sub>\n                    BrN\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    \u00b7Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u00b7CH\n                    <jats:sub>3<\/jats:sub>\n                    CN, the imidazole ring is in envelope conformation and the pyridine and phenyl rings are oriented at a dihedral angle of 72.52\u2005(5)\u00b0. In the crystal, O\u2014H...Cl and N\u2014H...Cl hydrogen bonds link the cations and anions into centrosymmetric tetramers enclosing\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    (12) loops. Short Br...Cl [3.2313\u2005(4)\u2005\u00c5] and O...Cl [3.0490\u2005(10)\u2005\u00c5] contacts are observed. A Hirshfeld surface analysis of the structure indicates that the most important contributions for the crystal packing are from H...H (52.4%), H...C\/C...H (12.1%), H...Br\/Br...H (11.0%) and H...Cl\/Cl...H (10.2%) interactions.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025005778","type":"journal-article","created":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T02:13:51Z","timestamp":1751336031000},"page":"672-675","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and structure of 6-bromo-2-(diethoxymethyl)-2-hydroxy-3-phenyl-2,3-dihydro-1\n                    <i>H<\/i>\n                    -imidazo[1,2-\n                    <i>a<\/i>\n                    ]pyridin-4-ium chloride acetonitrile monosolvate"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6769-0232","authenticated-orcid":true,"given":"Firudin I.","family":"Guseinov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6791-9973","authenticated-orcid":true,"given":"Aida I.","family":"Samigullina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8602-4382","authenticated-orcid":true,"given":"Tuncer","family":"H\u00f6kelek","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-7728-0441","authenticated-orcid":true,"given":"Sahil Z.","family":"Hamidov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jamal","family":"Lasri","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02ma4wv74","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khudayar I.","family":"Hasanov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tahir A.","family":"Javadzade","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alebel N.","family":"Belay","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,7,4]]},"reference":[{"key":"hb8130_bb1","doi-asserted-by":"crossref","first-page":"832","DOI":"10.1134\/S1061934808090049","volume":"63","author":"Alieva","year":"2008","journal-title":"J. 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