{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T08:12:44Z","timestamp":1761293564286,"version":"build-2065373602"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100009520","name":"Dr. Erich-Kr\u00fcger-Stiftung","doi-asserted-by":"crossref","award":["02110150, TUBAF"],"award-info":[{"award-number":["02110150, TUBAF"]}],"id":[{"id":"10.13039\/501100009520","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,7,18]]},"published-print":{"date-parts":[[2025,8,1]]},"abstract":"<jats:p>\n                    This article describes the crystal structures of 3,4,5-triphenyltoluene, C\n                    <jats:sub>25<\/jats:sub>\n                    H\n                    <jats:sub>20<\/jats:sub>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    ), and 3,4,5-triphenylbenzyl bromide, C\n                    <jats:sub>25<\/jats:sub>\n                    H\n                    <jats:sub>19<\/jats:sub>\n                    Br (\n                    <jats:bold>2<\/jats:bold>\n                    ), which represent two intermediates of a multistep synthesis of a phenylacetic acid derivative. Compound\n                    <jats:bold>1<\/jats:bold>\n                    crystallizes from methanol in two polymorphic forms, with the space groups\n                    <jats:italic>P<\/jats:italic>\n                    2\/\n                    <jats:italic>n<\/jats:italic>\n                    (\n                    <jats:bold>1a<\/jats:bold>\n                    ) and\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/c (\n                    <jats:bold>1b<\/jats:bold>\n                    ). In both cases, van der Waals forces significantly contribute to the cohesion of the crystal structure and the two polymorphs are characterized by similar modes of molecular interconnection. Compound\n                    <jats:bold>2<\/jats:bold>\n                    crystallizes from\n                    <jats:italic>n<\/jats:italic>\n                    -hexane in the space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    , showing a similar pattern of noncovalent interactions to\n                    <jats:bold>1a<\/jats:bold>\n                    and\n                    <jats:bold>1b<\/jats:bold>\n                    . In all reported structures, the aromatic framework of the molecules adopts a paddlewheel-like conformation.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025006462","type":"journal-article","created":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T07:44:53Z","timestamp":1753947893000},"page":"776-781","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of 3,4,5-triphenyltoluene and 3,4,5-triphenylbenzyl bromide"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-0788-4934","authenticated-orcid":true,"given":"Pierre","family":"Seidel","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eric","family":"Meier","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3571-7899","authenticated-orcid":true,"given":"Monika","family":"Mazik","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,7,31]]},"reference":[{"key":"jy2062_bb1","first-page":"1","volume":"16","author":"Agrawal","year":"2021","journal-title":"Nat. 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