{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T12:09:46Z","timestamp":1785413386662,"version":"3.56.0"},"reference-count":39,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2025,8,7]],"date-time":"2025-08-07T00:00:00Z","timestamp":1754524800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,8,7]],"date-time":"2025-08-07T00:00:00Z","timestamp":1754524800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,7,24]]},"published-print":{"date-parts":[[2025,9,1]]},"abstract":"<jats:p>\n                    Two new benzenesulfonyl derivatives,\n                    <jats:italic>N<\/jats:italic>\n                    -(2-iodophenyl)benzenesulfonamide, C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    INO\n                    <jats:sub>2<\/jats:sub>\n                    , (\n                    <jats:bold>I<\/jats:bold>\n                    ), and\n                    <jats:italic>N<\/jats:italic>\n                    -(4,5-difluoro-2-iodophenyl)benzenesulfonamide, C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    F\n                    <jats:sub>2<\/jats:sub>\n                    INO\n                    <jats:sub>2<\/jats:sub>\n                    S, (\n                    <jats:bold>II<\/jats:bold>\n                    ) were synthesized and structurally characterized. In both molecular structures, the conformation of the N\u2014C bond in the \u2013SO\n                    <jats:sub>2<\/jats:sub>\n                    \u2014NH\u2014C segment is\n                    <jats:italic>gauche<\/jats:italic>\n                    relative to the S=O bond. For (\n                    <jats:bold>I<\/jats:bold>\n                    ), the crystal packing is dominated by N\u2014H...O hydrogen-bonding interactions that link the molecules into chains extending parallel to [010]. In the case of (\n                    <jats:bold>II<\/jats:bold>\n                    ), the molecules are linked by N\u2014H...O(S) hydrogen bonds into dimers that are located on centers of inversion. These findings are consistent with the results of Hirshfeld surface analyses.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025006656","type":"journal-article","created":{"date-parts":[[2025,7,28]],"date-time":"2025-07-28T05:55:27Z","timestamp":1753682127000},"page":"811-815","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["The crystal structures and Hirshfeld surface analysis of the 2-iodophenyl- and 4,5-difluoro-2-iodophenyl derivatives of benzenesulfonamide"],"prefix":"10.1107","volume":"81","author":[{"given":"Sundarasamy","family":"Madhan","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"MohamedHanifa","family":"NizamMohideen","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vinayagam","family":"Pavunkumar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3758-4578","authenticated-orcid":true,"given":"Arasambattu K.","family":"MohanaKrishnan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04jmt9361","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,8,7]]},"reference":[{"key":"wm5762_bb1","doi-asserted-by":"crossref","first-page":"1293","DOI":"10.1107\/S0567740871003893","volume":"27","author":"Arora","year":"1971","journal-title":"Acta Cryst. B"},{"key":"wm5762_bb2","unstructured":"Bruker (2016). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"wm5762_bb3","doi-asserted-by":"crossref","first-page":"o2627","DOI":"10.1107\/S1600536812034009","volume":"68","author":"Chaithanya","year":"2012","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb4","doi-asserted-by":"crossref","first-page":"o2872","DOI":"10.1107\/S1600536812037798","volume":"68","author":"Chaithanya","year":"2012","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb5","doi-asserted-by":"crossref","first-page":"o3698","DOI":"10.1107\/S1600536807037415","volume":"63","author":"Chakkaravarthi","year":"2007","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb6","doi-asserted-by":"crossref","first-page":"1189","DOI":"10.1016\/j.ejmech.2009.11.029","volume":"45","author":"Chohan","year":"2010","journal-title":"Eur. J. Med. Chem."},{"key":"wm5762_bb7","doi-asserted-by":"crossref","first-page":"1922","DOI":"10.1002\/chem.201704730","volume":"24","author":"Dennis","year":"2018","journal-title":"Chem. Eur. J."},{"key":"wm5762_bb8","doi-asserted-by":"crossref","first-page":"1099","DOI":"10.1007\/s00044-019-02378-6","volume":"28","author":"Elgemeie","year":"2019","journal-title":"Med. Chem. Res."},{"key":"wm5762_bb9","doi-asserted-by":"crossref","first-page":"3714","DOI":"10.1016\/j.ejmech.2011.05.037","volume":"46","author":"El-Sayed","year":"2011","journal-title":"Eur. J. Med. Chem."},{"key":"wm5762_bb10","doi-asserted-by":"crossref","first-page":"256","DOI":"10.1107\/S0108768189012929","volume":"46","author":"Etter","year":"1990","journal-title":"Acta Cryst. B"},{"key":"wm5762_bb11","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"wm5762_bb12","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1107\/S010876810701395X","volume":"63","author":"Gelbrich","year":"2007","journal-title":"Acta Cryst. B"},{"key":"wm5762_bb13","doi-asserted-by":"crossref","first-page":"o476","DOI":"10.1107\/S1600536809003845","volume":"65","author":"Gowda","year":"2009","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb14","doi-asserted-by":"crossref","first-page":"o576","DOI":"10.1107\/S160053680900573X","volume":"65","author":"Gowda","year":"2009","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb15","doi-asserted-by":"crossref","first-page":"o877","DOI":"10.1107\/S1600536809010459","volume":"65","author":"Gowda","year":"2009","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb16","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"wm5762_bb17","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"wm5762_bb18","doi-asserted-by":"crossref","first-page":"o4205","DOI":"10.1107\/S1600536806033174","volume":"62","author":"Li","year":"2006","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb19","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"wm5762_bb20","doi-asserted-by":"crossref","first-page":"682","DOI":"10.1107\/S2056989024004985","volume":"80","author":"Madhan","year":"2024","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb21","doi-asserted-by":"crossref","first-page":"1198","DOI":"10.1107\/S2056989022010684","volume":"78","author":"Madhan","year":"2022","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb22","doi-asserted-by":"crossref","first-page":"521","DOI":"10.1107\/S2056989023003821","volume":"79","author":"Madhan","year":"2023","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb23","doi-asserted-by":"crossref","first-page":"741","DOI":"10.1107\/S2056989023006096","volume":"79","author":"Madhan","year":"2023","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb24","doi-asserted-by":"crossref","first-page":"845","DOI":"10.1107\/S2056989024006649","volume":"80","author":"Madhan","year":"2024","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb25","doi-asserted-by":"crossref","first-page":"1110","DOI":"10.1107\/S2056989024009587","volume":"80","author":"Madhan","year":"2024","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb26","doi-asserted-by":"crossref","unstructured":"McKinnon, J. J., Jayatilaka, D. & Spackman, M. A. (2007). Chem. Commun. pp. 3814.","DOI":"10.1039\/b704980c"},{"key":"wm5762_bb27","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.1126\/science.1131943","volume":"317","author":"M\u00fcller","year":"2007","journal-title":"Science"},{"key":"wm5762_bb28","doi-asserted-by":"crossref","first-page":"o780","DOI":"10.1107\/S1600536806002303","volume":"62","author":"Perlovich","year":"2006","journal-title":"Acta Cryst. E"},{"key":"wm5762_bb29","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1039\/B610213C","volume":"37","author":"Purser","year":"2008","journal-title":"Chem. Soc. Rev."},{"key":"wm5762_bb30","doi-asserted-by":"crossref","first-page":"925","DOI":"10.2174\/0929867033457647","volume":"10","author":"Scozzafava","year":"2003","journal-title":"Curr. Med. Chem."},{"key":"wm5762_bb31","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/S0014-2999(99)00922-X","volume":"389","author":"Seri","year":"2000","journal-title":"Eur. J. Pharmacol."},{"key":"wm5762_bb32","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm5762_bb33","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm5762_bb34","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."},{"key":"wm5762_bb35","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"wm5762_bb36","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1517\/13543784.12.2.283","volume":"12","author":"Supuran","year":"2003","journal-title":"Expert Opin. Investig. Drugs"},{"key":"wm5762_bb37","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1038\/ja.2009.52","volume":"62","author":"Tatsuta","year":"2009","journal-title":"J. Antibiot."},{"key":"wm5762_bb38","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"wm5762_bb39","doi-asserted-by":"crossref","first-page":"3950","DOI":"10.1016\/j.bmcl.2016.07.006","volume":"26","author":"Zhao","year":"2016","journal-title":"Bioorg. Med. Chem. Lett."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/09\/00\/wm5762\/wm5762.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/09\/00\/wm5762\/wm5762.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T15:20:27Z","timestamp":1757085627000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989025006656"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8,7]]},"references-count":39,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2025,9]]}},"alternative-id":["S2056989025006656"],"URL":"https:\/\/doi.org\/10.1107\/s2056989025006656","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989025006656\/wm5762sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025006656\/wm5762Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025006656\/wm5762IIsup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025006656\/wm5762Isup4.cml","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025006656\/wm5762IIsup5.cml","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,8,7]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5762","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"30 June 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 July 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"7 August 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5762"}},{"value":"\u00a9 2025 Madhan\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}