{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T18:22:26Z","timestamp":1790792546322,"version":"4.1.0"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["2215812"],"award-info":[{"award-number":["2215812"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,7,24]]},"published-print":{"date-parts":[[2025,8,1]]},"abstract":"<jats:p>\n                    Bis(triphenylsulfonium) tetrachloridomanganate(II), (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>I<\/jats:bold>\n                    ), triphenylsulfonium tetrachloridoferrate(III), (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S)[FeCl\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>II<\/jats:bold>\n                    ), and bis(triphenylsulfonium) tetrachloridocobaltate(II), (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    [CoCl\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>III<\/jats:bold>\n                    ), crystallize in the monoclinic space groups\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    [(\n                    <jats:bold>I<\/jats:bold>\n                    ) and (\n                    <jats:bold>III<\/jats:bold>\n                    )] and\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    [(\n                    <jats:bold>II<\/jats:bold>\n                    )]. Compounds (\n                    <jats:bold>I<\/jats:bold>\n                    ) and (\n                    <jats:bold>III<\/jats:bold>\n                    ) each contain two crystallographically independent triphenylsulfonium (TPS\n                    <jats:sup>+<\/jats:sup>\n                    ) cations in the asymmetric unit, whereas (\n                    <jats:bold>II<\/jats:bold>\n                    ) has one. In all three compounds, the sulfonium centers adopt distorted trigonal\u2013pyramidal geometries, with S\u2014C bond lengths falling roughly in the 1.78\u20131.79\u2005\u00c5 range and C\u2014S\u2014C angles observed at about 101 to 106\u00b0. The [\n                    <jats:italic>M<\/jats:italic>\n                    Cl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\n                      <jats:italic>n<\/jats:italic>\n                      \u2212\n                    <\/jats:sup>\n                    anions (\n                    <jats:italic>M<\/jats:italic>\n                    = Mn\n                    <jats:sup>2+<\/jats:sup>\n                    , Fe\n                    <jats:sup>3+<\/jats:sup>\n                    , Co\n                    <jats:sup>2+<\/jats:sup>\n                    ;\n                    <jats:italic>n<\/jats:italic>\n                    = 2,1,2) adopt slightly distorted tetrahedral geometries, with\n                    <jats:italic>M<\/jats:italic>\n                    \u2014Cl bond lengths in the 2.19\u20132.38\u2005\u00c5 range and Cl\u2014\n                    <jats:italic>M<\/jats:italic>\n                    \u2014Cl angles of approximately 104\u2013113\u00b0. Hirshfeld surface analyses shows that H...H and H...C contacts dominate the TPS\n                    <jats:sup>+<\/jats:sup>\n                    cation environments, whereas H...Cl and short\n                    <jats:italic>M<\/jats:italic>\n                    \u2014S interactions link each [\n                    <jats:italic>M<\/jats:italic>\n                    Cl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\n                      <jats:italic>n<\/jats:italic>\n                      \u2212\n                    <\/jats:sup>\n                    anion to the surrounding cations. In (\n                    <jats:bold>I<\/jats:bold>\n                    ) and (\n                    <jats:bold>III<\/jats:bold>\n                    ), inversion-centered \u03c0\u2013\u03c0 stacking further consolidates the crystal packing, while in (\n                    <jats:bold>II<\/jats:bold>\n                    ) no \u03c0\u2013\u03c0 interactions are observed.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025006668","type":"journal-article","created":{"date-parts":[[2025,7,28]],"date-time":"2025-07-28T06:02:58Z","timestamp":1753682578000},"page":"770-775","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II)"],"prefix":"10.1107","volume":"81","author":[{"given":"Waylan","family":"Callaway","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew","family":"Elterman","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikita","family":"Krasilnikov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gavin","family":"Roberts","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Davis","family":"Rutan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ty","family":"Spencer","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8373-1495","authenticated-orcid":true,"given":"Clifford W.","family":"Padgett","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3494-8652","authenticated-orcid":true,"given":"Will E.","family":"Lynch","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04agmb972","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,7,31]]},"reference":[{"key":"ny2014_bb1","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1107\/S2056989025000118","volume":"81","author":"Artis","year":"2025","journal-title":"Acta Cryst. 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