{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,11]],"date-time":"2025-09-11T18:38:17Z","timestamp":1757615897462,"version":"3.44.0"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2025,8,7]],"date-time":"2025-08-07T00:00:00Z","timestamp":1754524800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,8,7]],"date-time":"2025-08-07T00:00:00Z","timestamp":1754524800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,8,1]]},"published-print":{"date-parts":[[2025,9,1]]},"abstract":"<jats:p>The title compound, C<jats:sub>9<\/jats:sub>H<jats:sub>12<\/jats:sub>NO<jats:sup>+<\/jats:sup>\u00b7Br<jats:sup>\u2212<\/jats:sup>\u00b7CBr<jats:sub>4<\/jats:sub>, consists of one 4-formyl-<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylbenzenaminium bromide and a tetrabromomethane molecule. In the crystal, the bromide ions link 4-formyl-<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylbenzenaminium moieties through intermolecular C\u2014H...Br and N\u2014H...Br hydrogen bonds, while intermolecular C\u2014H...O hydrogen bonds link 4-formyl-<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylbenzenaminium cations, enclosing <jats:italic>R<\/jats:italic>\n                  <jats:sup>2<\/jats:sup>\n                  <jats:sub>2<\/jats:sub>(18) ring motifs, into a di-periodic network structure. The tetrabromomethane molecules fill the spaces between the layers. Neither \u03c0\u2013\u03c0 nor C\u2014H...\u03c0(ring) interactions are observed. A Hirshfeld surface analysis of the crystal structure indicates that the most abundant contacts contributing to the crystal packing are from H...Br\/Br...H (56.0%), Br...Br (12.1%), H...O\/O...H (9.7%) and H...H (9.5%) interactions.<\/jats:p>","DOI":"10.1107\/s2056989025006929","type":"journal-article","created":{"date-parts":[[2025,8,4]],"date-time":"2025-08-04T05:06:23Z","timestamp":1754283983000},"page":"806-810","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of a supramolecular aggregate of 4-formyl-<i>N<\/i>,<i>N<\/i>-dimethylanilinium bromide with tetrabromomethane"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1415-8012","authenticated-orcid":true,"given":"Atash V.","family":"Gurbanov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tuncer","family":"H\u00f6kelek","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gunay Z.","family":"Mammadova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Khudayar I.","family":"Hasanov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tahir A.","family":"Javadzade","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alebel N.","family":"Belay","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,8,7]]},"reference":[{"key":"pk2717_bb1","unstructured":"Bruker (2014). 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