{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T16:16:37Z","timestamp":1785428197949,"version":"3.56.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2025,8,15]],"date-time":"2025-08-15T00:00:00Z","timestamp":1755216000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,8,15]],"date-time":"2025-08-15T00:00:00Z","timestamp":1755216000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Vission Group of Science and Technology"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,8,5]]},"published-print":{"date-parts":[[2025,9,1]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>26<\/jats:sub>\n                    H\n                    <jats:sub>32<\/jats:sub>\n                    BrClO\n                    <jats:sub>3<\/jats:sub>\n                    , the dihedral angle between the 4-bromo-2-chlorophenyl ring and the aromatic ring of (alkyloxy)phenyl moiety is found to be 77.21\u2005(2)\u00b0. The torsion angle associated with the ester moiety is 173.2\u2005(2)\u00b0 which is\n                    <jats:italic>anti-periplanar<\/jats:italic>\n                    . In the crystal, intermolecular C\u2014H...O hydrogen bonding links the molecules into cyclic hydrogen-bonded inversion dimers with\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (10) motifs. The molecular structure is associated with an inversion centre and connected through two symmetrical C\u2014H...O interactions, forming\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (10) inversion dimer motif. The packing is further consolidated by C\u2014H...\u03c0 and C\u2014Cl...\u03c0 interactions. Hirshfeld surface analysis showed that the most significant contributions are from H...H (54.0%), C...H\/H...C (15.2%), Br...H\/H...Br (10.9%), O...H\/H...O (7.8%) and Cl...H\/H...Cl (2.6%) contacts.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025007078","type":"journal-article","created":{"date-parts":[[2025,8,12]],"date-time":"2025-08-12T10:10:32Z","timestamp":1754993432000},"page":"836-839","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure and Hirshfeld surface analysis of 4-bromo-2-chlorophenyl (\n                    <i>E<\/i>\n                    )-3-[4-(undecyloxy)phenyl]acrylate"],"prefix":"10.1107","volume":"81","author":[{"given":"H. C.","family":"Devarajegowda","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/012bxv356","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"B. 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