{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T11:22:13Z","timestamp":1785410533544,"version":"3.56.0"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,8,20]]},"published-print":{"date-parts":[[2025,10,1]]},"abstract":"<jats:p>\n                    The unit cell of the title compound, [Ni(C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    BrN\n                    <jats:sub>6<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b72CH\n                    <jats:sub>3<\/jats:sub>\n                    OH, contains a neutral complex and two methanol molecules. The Ni\n                    <jats:sup>II<\/jats:sup>\n                    ion adopts a pseudooctahedral geometry, coordinated by two tridentate ligands\n                    <jats:italic>via<\/jats:italic>\n                    pyrazole, pyridine, and triazole N atoms. The average Ni\u2014N bond length is 2.097\u2005(4)\u2005\u00c5. In the crystal, molecules form supramolecular chains through weak C\u2013H...\u03c0 interactions and further assemble into diperiodic layers\n                    <jats:italic>via<\/jats:italic>\n                    C\u2014H...N\/C interactions. Hirshfeld surface analysis shows H...H (32.1%), H...C\/C...H (27.3%), H...N\/N...H (14.9%), and H...Br\/Br...H (14.6%) contacts. Interaction energies were evaluated using HF\/3\u201321\u2005G energy frameworks analysis. Structural parameters were compared to those of the chloro-containing analogue, and the effect of substituent variation was discussed.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025007467","type":"journal-article","created":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T07:20:56Z","timestamp":1757056856000},"page":"906-911","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure, Hirshfeld surface analysis, and energy framework of bis{3-(4-bromophenyl)-5-[6-(1\n                    <i>H<\/i>\n                    -pyrazol-1-yl)pyridin-2-yl]-4\n                    <i>H<\/i>\n                    -1,2,4-triazol-4-ido}nickel(II) methanol disolvate and comparison with its chloro-substituted analogue"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4818-8658","authenticated-orcid":true,"given":"Kateryna","family":"Znovjyak","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1222-4373","authenticated-orcid":true,"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0561n6946","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergiy O.","family":"Nikitin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6073-002X","authenticated-orcid":true,"given":"Yurii S.","family":"Moroz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5109-3823","authenticated-orcid":true,"given":"Oksana","family":"Tananaiko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey O.","family":"Malinkin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maksym","family":"Seredyuk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,9,5]]},"reference":[{"key":"ee2019_bb1","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. 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