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The compound readily crystallizes from a concentrated hexanes solution in high yield. The imine bond is nearly planar with the 2-bromophenyl group, while the\n                    <jats:italic>N<\/jats:italic>\n                    -(3,5-bis(trifluoromethyl)phenyl moiety is significantly twisted from the imine group [49.61\u2005(5)\u00b0]. The crystal packing involves short intermolecular C\u2014H...Br contacts linking zigzag ribbons flanked by fluorous layers.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025007650","type":"journal-article","created":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T07:20:56Z","timestamp":1757056856000},"page":"916-919","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of (\n                    <i>E<\/i>\n                    )-\n                    <i>N<\/i>\n                    -[(2-bromophenyl)methylidene]-3,5-bis(trifluoromethyl)aniline"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7026-1319","authenticated-orcid":true,"given":"Nicholas B.","family":"Kingsley","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6885-7487","authenticated-orcid":true,"given":"Tyler J.","family":"Doyon","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5584-1961","authenticated-orcid":true,"given":"Daron E.","family":"Janzen","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03x1f1d90","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,9,5]]},"reference":[{"key":"ej2015_bb1","unstructured":"Bruker (2017). 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