{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:27:45Z","timestamp":1785403665413,"version":"3.56.0"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:00:00Z","timestamp":1760400000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:00:00Z","timestamp":1760400000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["2400361"],"award-info":[{"award-number":["2400361"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["1847926"],"award-info":[{"award-number":["1847926"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["1040566"],"award-info":[{"award-number":["1040566"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100011956","name":"Agricultural Research Institute, California State University","doi-asserted-by":"publisher","award":["26-04-116"],"award-info":[{"award-number":["26-04-116"]}],"id":[{"id":"10.13039\/100011956","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,10,1]]},"published-print":{"date-parts":[[2025,11,1]]},"abstract":"<jats:p>\n                    A\n                    <jats:italic>\u03bc<\/jats:italic>\n                    -oxo vanadium(V) dimeric complex, \u03bc-oxido-bis[(2,2\u2032-{[ethane-1,2-diylbis(azanediyl)]bis(methylene)}diphenolato)oxidovanadium(V)], [V\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ), was crystallized by slow evaporation from an ethanol solution. The\n                    <jats:italic>\u03bc<\/jats:italic>\n                    -oxo dimer crystallizes in the monoclinic space group\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>c<\/jats:italic>\n                    where the salan ligand\n                    <jats:bold>1a<\/jats:bold>\n                    coordinates to the vanadium center in a \u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    ,\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>O<\/jats:italic>\n                    fashion, forming a distorted octahedral geometry. The bridging oxo ligand lies on a crystallographic twofold axis. The unit cell consists of four molecules of\n                    <jats:bold>1<\/jats:bold>\n                    that are linked by C\u2014H...\u00b7\u03c0\n                    <jats:sub>arene<\/jats:sub>\n                    interactions as well as intramolecular hydrogen bonding.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025008631","type":"journal-article","created":{"date-parts":[[2025,10,2]],"date-time":"2025-10-02T07:01:02Z","timestamp":1759388462000},"page":"1014-1017","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a \u03bc-oxo vanadium(V) dimer coordinated by a salan ligand"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-2976-385X","authenticated-orcid":true,"given":"Isha A.","family":"Kallingal","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05by5hm18","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anais A.","family":"Alvarado","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05by5hm18","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3778-207X","authenticated-orcid":true,"given":"S. Chantal E.","family":"Stieber","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05by5hm18","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alex","family":"John","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05by5hm18","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,10,14]]},"reference":[{"key":"tx2104_bb1","doi-asserted-by":"crossref","first-page":"3542","DOI":"10.1021\/ic8017985","volume":"48","author":"Ad\u00e3o","year":"2009","journal-title":"Inorg. Chem."},{"key":"tx2104_bb2","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0162-0134(00)00032-5","volume":"80","author":"Baran","year":"2000","journal-title":"J. Inorg. Biochem."},{"key":"tx2104_bb3","unstructured":"Bruker (2020). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"tx2104_bb4","unstructured":"Bruker (2023). APEX5. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"tx2104_bb5","doi-asserted-by":"crossref","first-page":"1937","DOI":"10.1021\/cr00021a014","volume":"93","author":"Butler","year":"1993","journal-title":"Chem. Rev."},{"key":"tx2104_bb6","doi-asserted-by":"crossref","first-page":"8199","DOI":"10.1039\/c3cc44656e","volume":"49","author":"Chapman","year":"2013","journal-title":"Chem. Commun."},{"key":"tx2104_bb7","doi-asserted-by":"crossref","first-page":"2232","DOI":"10.1016\/j.ccr.2011.05.009","volume":"255","author":"da Silva","year":"2011","journal-title":"Coord. Chem. Rev."},{"key":"tx2104_bb8","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1016\/j.ica.2018.04.044","volume":"480","author":"Debnath","year":"2018","journal-title":"Inorg. Chim. Acta"},{"key":"tx2104_bb9","doi-asserted-by":"crossref","first-page":"9807","DOI":"10.1021\/acs.inorgchem.8b01530","volume":"57","author":"Dereli","year":"2018","journal-title":"Inorg. Chem."},{"key":"tx2104_bb10","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"tx2104_bb11","doi-asserted-by":"crossref","first-page":"e202303255","DOI":"10.1002\/slct.202303255","volume":"9","author":"Drze\u017cd\u017con","year":"2024","journal-title":"ChemistrySelect"},{"key":"tx2104_bb12","doi-asserted-by":"crossref","first-page":"3013","DOI":"10.1021\/cr950057h","volume":"96","author":"Eady","year":"1996","journal-title":"Chem. Rev."},{"key":"tx2104_bb13","doi-asserted-by":"crossref","first-page":"1901","DOI":"10.1021\/acscatal.5b02667","volume":"6","author":"Gopaladasu","year":"2016","journal-title":"ACS Catal."},{"key":"tx2104_bb14","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"tx2104_bb15","doi-asserted-by":"crossref","first-page":"108134","DOI":"10.1016\/j.inoche.2020.108134","volume":"119","author":"Hasnaoui","year":"2020","journal-title":"Inorg. Chem. Commun."},{"key":"tx2104_bb16","doi-asserted-by":"crossref","first-page":"7006","DOI":"10.1002\/chem.200700354","volume":"13","author":"Hoppe","year":"2007","journal-title":"Chem. A Eur. J."},{"key":"tx2104_bb17","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.ica.2018.11.049","volume":"487","author":"Hossain","year":"2019","journal-title":"Inorg. Chim. Acta"},{"key":"tx2104_bb18","doi-asserted-by":"crossref","first-page":"1375","DOI":"10.1016\/j.poly.2011.02.005","volume":"30","author":"Hosseini Monfared","year":"2011","journal-title":"Polyhedron"},{"key":"tx2104_bb19","doi-asserted-by":"crossref","first-page":"4353","DOI":"10.1021\/acs.chemrev.2c00546","volume":"123","author":"Hu","year":"2023","journal-title":"Chem. Rev."},{"key":"tx2104_bb20","doi-asserted-by":"crossref","first-page":"1118","DOI":"10.1039\/C1DT11535A","volume":"41","author":"Hu","year":"2012","journal-title":"Dalton Trans."},{"key":"tx2104_bb21","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"tx2104_bb22","doi-asserted-by":"crossref","first-page":"4494","DOI":"10.1016\/j.poly.2007.06.010","volume":"26","author":"Maity","year":"2007","journal-title":"Polyhedron"},{"key":"tx2104_bb23","doi-asserted-by":"crossref","first-page":"111582","DOI":"10.1016\/j.jinorgbio.2021.111582","volume":"224","author":"Patra","year":"2021","journal-title":"J. Inorg. Biochem."},{"key":"tx2104_bb24","doi-asserted-by":"crossref","first-page":"5241","DOI":"10.1039\/c2dt11514j","volume":"41","author":"Reytman","year":"2012","journal-title":"Dalton Trans."},{"key":"#cr-split#-tx2104_bb25.1","unstructured":"SciFinder (2025). Chemical Abstracts Service: Colombus, OH, 2010"},{"key":"#cr-split#-tx2104_bb25.2","unstructured":"RN 58-08-2 (accessed August 1, 2025)."},{"key":"tx2104_bb26","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"tx2104_bb27","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"tx2104_bb28","doi-asserted-by":"crossref","first-page":"2186","DOI":"10.1021\/cs5003788","volume":"4","author":"Steelman","year":"2014","journal-title":"ACS Catal."},{"key":"tx2104_bb29","doi-asserted-by":"crossref","first-page":"6280","DOI":"10.1021\/ja401474v","volume":"135","author":"Steelman","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"tx2104_bb30","doi-asserted-by":"crossref","first-page":"3660","DOI":"10.1039\/D4CY00441H","volume":"14","author":"Wagner","year":"2024","journal-title":"Catal. Sci. Technol."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/11\/00\/tx2104\/tx2104.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2025\/11\/00\/tx2104\/tx2104.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T14:37:11Z","timestamp":1762353431000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989025008631"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,14]]},"references-count":31,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2025,11]]}},"alternative-id":["S2056989025008631"],"URL":"https:\/\/doi.org\/10.1107\/s2056989025008631","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989025008631\/tx2104sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989025008631\/tx2104Isup3.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,14]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?tx2104","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"27 August 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"1 October 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"14 October 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?tx2104"}},{"value":"\u00a9 2025 Kallingal\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}