{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T14:42:33Z","timestamp":1762353753839,"version":"build-2065373602"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2025,10,31]],"date-time":"2025-10-31T00:00:00Z","timestamp":1761868800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,10,31]],"date-time":"2025-10-31T00:00:00Z","timestamp":1761868800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Baku State University Azerbaijan"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,10,21]]},"published-print":{"date-parts":[[2025,11,1]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>19<\/jats:sub>\n                    H\n                    <jats:sub>14<\/jats:sub>\n                    ClFO\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    , the molecular conformation is stabilized by intramolecular C\u2014H...F, C\u2014H...Cl and C\u2014H...O hydrogen bonds. In the crystal, the molecules are linked into [010] chains by C\u2014H...O hydrogen bonds, creating a\n                    <jats:italic>C<\/jats:italic>\n                    (6) motif and weak C\u2014H...F and C\u2014H...Cl interactions link these chains into sheets parallel to the (100) plane. The entire \u2013C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    FCl group is disordered over two positions in a 0.931\u2005(4):0.069\u2005(4) ratio. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H (26.7%), C...H\/H...C (17.2%), S...H\/H...S (15.0%) and O...H\/H...O (12.0%) interactions.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025009284","type":"journal-article","created":{"date-parts":[[2025,10,23]],"date-time":"2025-10-23T07:45:41Z","timestamp":1761205541000},"page":"1094-1098","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of 3-(2-chloro-6-fluorophenyl)-1,5-bis(thiophen-2-yl)pentane-1,5-dione"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1415-8012","authenticated-orcid":true,"given":"Atash V.","family":"Gurbanov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2421-0929","authenticated-orcid":true,"given":"Mehmet","family":"Akkurt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nurlana D.","family":"Sadikhova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6098-9450","authenticated-orcid":true,"given":"Gizachew Mulugeta","family":"Manahelohe","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,10,31]]},"reference":[{"key":"oi2026_bb1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/anie.199515551","volume":"34","author":"Bernstein","year":"1995","journal-title":"Angew. 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