{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T22:32:11Z","timestamp":1788820331642,"version":"build-2803163510"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,11,29]]},"published-print":{"date-parts":[[2026,1,1]]},"abstract":"<jats:p>\n                    The first title compound, C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    FN\n                    <jats:sub>2<\/jats:sub>\n                    OS, crystallizes in space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    with two independent molecules in the asymmetric unit, which form a dimer with an\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (8) motif through pairwise N\u2014H...N hydrogen bonds. In the crystal of (I), N\u2014H...O hydrogen bonds bind the dimers into zigzag ribbons running along the [100] direction, generating\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>4<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    (14) motifs. The second title compound, C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    ClN\n                    <jats:sub>2<\/jats:sub>\n                    OS (space group\n                    <jats:italic>I<\/jats:italic>\n                    2\/\n                    <jats:italic>a<\/jats:italic>\n                    ), contains one molecule in the asymmetric unit, which forms a dimer with an\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (8) motif\n                    <jats:italic>via<\/jats:italic>\n                    inversion symmetry. In the extended structure, the molecules form zigzag ribbons in the [100] direction by N\u2014H...N and N\u2014H...O hydrogen bonds, resulting in consecutive\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>4<\/jats:sup>\n                    <jats:sub>1<\/jats:sub>\n                    (8)\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>1<\/jats:sub>\n                    (5)\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (8)\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>1<\/jats:sub>\n                    (5)\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>4<\/jats:sup>\n                    <jats:sub>1<\/jats:sub>\n                    (8) motifs. The Hirshfeld surface analyses of the compounds (I) and (II) indicates that the most important factors influencing the crystal packing are H...H interactions [21.1% for molecule\n                    <jats:italic>A<\/jats:italic>\n                    of (I), 20.3% for molecule\n                    <jats:italic>B<\/jats:italic>\n                    of (I) and 21.0% for (II)].\n                  <\/jats:p>","DOI":"10.1107\/s2056989025010667","type":"journal-article","created":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T07:47:31Z","timestamp":1764748051000},"page":"14-18","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Consistent supramolecular motifs and different local symmetries in the structures of 2-amino-5-(4-fluorophenyl)-1,3-thiazole-4-carbaldehyde and 2-amino-5-(4-chlorophenyl)-1,3-thiazole-4-carbaldehyde"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6769-0232","authenticated-orcid":true,"given":"Firudin I.","family":"Guseinov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ksenia A.","family":"Afanaseva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4290-2961","authenticated-orcid":true,"given":"Sergey M.","family":"Gaidar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02b4gv182","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anna M.","family":"Pikina","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02b4gv182","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2421-0929","authenticated-orcid":true,"given":"Mehmet","family":"Akkurt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fargana S.","family":"Aliyeva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khudayar I.","family":"Hasanov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4175-5656","authenticated-orcid":true,"given":"Alebel N.","family":"Belay","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,1]]},"reference":[{"key":"hb8159_bb1","doi-asserted-by":"crossref","first-page":"o776","DOI":"10.1107\/S2056989015017454","volume":"71","author":"Akkurt","year":"2015","journal-title":"Acta Cryst. 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