{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T11:50:50Z","timestamp":1785412250721,"version":"3.56.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,11,30]]},"published-print":{"date-parts":[[2026,1,1]]},"abstract":"<jats:p>\n                    The title compound, [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    ClN\n                    <jats:sub>4<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    ](ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7CH\n                    <jats:sub>3<\/jats:sub>\n                    CN, consists of one centrosymmetric cationic dinuclear zinc(II) complex with two pentadentate ligands containing quinolin-8-olato and bis(pyridin-2-ylmethyl)amine groups, two perchlorate counter-ions and one acetonitrile solvate molecule. The Zn\n                    <jats:sup>II<\/jats:sup>\n                    atom adopts a distorted octahedral geometry and coordinates the O atom and the N atom of the quinolin-8-olato group and three N atoms of the bis(pyridin-2-ylmethyl)amine group in a ligand, and the O atom in an adjacent ligand generated by an inversion operation. The phenolato oxygen atoms in the two ligands of the cationic dinuclear complex are bridging coordinated with the two Zn\n                    <jats:sup>II<\/jats:sup>\n                    atoms. In the crystal, the cationic dinuclear complex molecules and perchlorate ions are linked by C\u2014H...Cl and C\u2014H...O hydrogen bonds, forming a three-dimensional network.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025010680","type":"journal-article","created":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T16:50:51Z","timestamp":1764607851000},"page":"5-9","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of bis[\u03bc\n                    <sub>2<\/sub>\n                    -7-({bis[(pyridin-2-yl)methyl]amino-\u03ba\n                    <sup>3<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032,\n                    <i>N<\/i>\n                    \u2032\u2032}methyl)-5-chloroquinolin-8-olato-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>O<\/i>\n                    ]dizinc(II) bis(perchlorate) acetonitrile monosolvate"],"prefix":"10.1107","volume":"82","author":[{"given":"Koji","family":"Kubono","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keita","family":"Tani","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/051j8zv27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4122-3345","authenticated-orcid":true,"given":"Yukiyasu","family":"Kashiwagi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03r38cy24","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,1]]},"reference":[{"key":"jp2022_bb1","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1107\/S0108768102003324","volume":"58","author":"Bruno","year":"2002","journal-title":"Acta Cryst. 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Rigaku Oxford Diffraction Ltd, Yarnton, England."},{"key":"jp2022_bb12","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1016\/j.poly.2012.11.027","volume":"58","author":"Royzen","year":"2013","journal-title":"Polyhedron"},{"key":"jp2022_bb13","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jp2022_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"jp2022_bb15","doi-asserted-by":"crossref","first-page":"18893","DOI":"10.1039\/C5DT02894A","volume":"44","author":"Shen","year":"2015","journal-title":"Dalton Trans."},{"key":"jp2022_bb16","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S2056989019016244","volume":"76","author":"Spek","year":"2020","journal-title":"Acta Cryst. 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