{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,4]],"date-time":"2026-07-04T01:52:58Z","timestamp":1783129978111,"version":"3.54.6"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,12,5]]},"published-print":{"date-parts":[[2026,1,1]]},"abstract":"<jats:p>\n                    The syntheses and structures of 2-fluorobenzyl (\n                    <jats:italic>Z<\/jats:italic>\n                    )-2-(2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate dimethyl sulfoxide monosolvate, C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    FN\n                    <jats:sub>3<\/jats:sub>\n                    OS\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    OS (\n                    <jats:bold>1<\/jats:bold>\n                    ) and 2-fluorobenzyl (\n                    <jats:italic>Z<\/jats:italic>\n                    )-2-(5-bromo-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate, C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    BrFN\n                    <jats:sub>3<\/jats:sub>\n                    OS\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>2<\/jats:bold>\n                    ) are reported. Both structures feature a\n                    <jats:italic>Z<\/jats:italic>\n                    -configuration with respect to the C=N bond and the fluorobenzyl ring is approximately orthogonal to the isatin moiety. For\n                    <jats:bold>1<\/jats:bold>\n                    , the crystal packing features weak C\n                    <jats:sub>ar<\/jats:sub>\n                    \u2014H...S (ar = aromatic) hydrogen bonds that link adjacent molecules in a\n                    <jats:italic>C<\/jats:italic>\n                    (10) fashion to form pleated chains propagating along [001] and short S...O contacts between dimethyl sulfoxide solvent molecules forming chains along [010]. The N\u2014H hydrogen bond donors in\n                    <jats:bold>1<\/jats:bold>\n                    form either intramolecular or discrete N\u2014H...O\n                    <jats:sub>(DMSO)<\/jats:sub>\n                    hydrogen bonds. In\n                    <jats:bold>2<\/jats:bold>\n                    , alternating\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (8)-type pairwise N\u2014H...O hydrogen bonds and short F...Br contacts link the molecules into chains propagating along [2\n                    <jats:overline>1<\/jats:overline>\n                    0]. The later unsolvated structure is of notably poorer quality and exhibits disorder in its\n                    <jats:italic>o<\/jats:italic>\n                    -fluorobenzyl group, with a 180\u00b0 flip and a small twist around the S\u2014C bond. These findings are consistent with the results of Hirshfeld surface analyses.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025011028","type":"journal-article","created":{"date-parts":[[2025,12,8]],"date-time":"2025-12-08T13:39:53Z","timestamp":1765201193000},"page":"72-76","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Different intermolecular interactions in solvated and unsolvated isatin-based dithiocarbazate imine derivatives"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8578-7054","authenticated-orcid":true,"given":"Aidan P.","family":"McKay","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5366-9168","authenticated-orcid":true,"given":"David B.","family":"Cordes","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohd Abdul","family":"Fatah Abdul Manan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,1]]},"reference":[{"key":"hb8175_bb1","doi-asserted-by":"crossref","unstructured":"Abdul Manan, M. 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